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专家信息 教学情况 科学研究 论文专著 荣誉奖励 实验室项目合作

专家信息:


赵可清,男,1966年8月出生于重庆开县。四川师范大学首席教授、博士、研究生导师。化学硕士点负责人。有机光电功能材料四川省科技创新团队负责人。四川省教育厅科技创新团队和四川师范大学重点建设科研团队负责人。四川省高校先进功能材料重点实验室主任、学术委员。曾在台湾大学、德国和日本进行科研工作。在盘状液晶、全氟烃链液晶、点击化学以及聚乙炔高分子液晶的分子设计、合成及性能研究领域进行了深入研究。已发表SCI收录学术论文100余篇。E-mail: kqzhao@sicnu.edu.cn。Tel.:136 9906 7543.

教育及工作经历:

2002/9-2003/8,日本国立产业技术总合研究所(AIST),大阪府池田市,访问研究。

2001/8–2002/3,德国达姆斯达特工业大学(TU Darmstadt),博士后。

1998/3-1999/6,台湾大学化学系,博士后。

1994/9-1997/12,四川大学化学系(中国科学院成都有机所),攻读博士学位。

1988/9-1991/7, 华东师范大学化学系,攻读硕士学位。

1984/9-1988/7, 四川师范大学化学系,攻读学士学位。

2002/12,晋升为四川师范大学教授。

2005/1-2012/12,四川师范大学第一届、第二届特聘教授。

2013/1,四川师范大学第三届首席教授。

学术兼职:

1、中国化学会会员。

2、国际液晶学会会员。

3、中国化学会会员。

4、中国物理学会会员。

5、中国物理学会液晶分委员会委员。

6、四川师范大学学术(教授)委员会委员。

7、四川师范大学图书馆建设委员会委员。

8、四川师范大学学报(自然科学版)编委。

教学工作:


主讲课程:

四川师范大学硕士研究生精品课程《高等有机化学》负责人。

“有机化学”四川省双语示范课程。

“盘状液晶合成及性能”国家级大学生创新性实验项目负责人。

主讲《有机合成》(双语);《有机化学》;《有机化学实验》;《有机合成》;《有机反应机理》;《高等有机化学》;《金属有机化学与催化》;《化学专业英语》。

培养学生获奖:

指导大学生廖雨亭等获四川省挑战杯一等奖、全国大学生挑战杯三等奖。

指导大学生王理获得四川省挑战杯三等奖。

指导硕士白跃峰获四川省和四川师范大学优秀硕士论文。

指导高彩艳、刘兆军获四川师范大学优秀硕士学位论文。

国际化学奥林匹克竞赛

作为副领队,和段联运教授(北京大学) 汪必琴教授(四川师范大学), 王颖霞副教授(北京大学)一起, 带领中国代表队参加2007年莫斯科国际中学生化学奥林匹克竞赛 ( IChO-39 Moscow: International Chemistry Olympiad ) 取得优异成绩: 四位中学生选手全都获得金牌; 排名第一, 第二, 第五, 第十四. 中国队在参加的70个国家中, 总分排名第一,为国家争得荣誉。

第39届国际化学奥林匹克理论试题,化学教育,2007,(9),55-62。

第39届国际化学奥林匹克实验试题,化学教育,2007,(10),56-59。

培养研究生情况:

在化学和材料学专业培养研究生数十名。

科学研究:


研究方向:

有机液晶半导体材料合成、自组装有序结构与光电性能研究。

主要科研工作:

(1)金属有机、有机小分子光电子功能材料的分子设计、合成、结构与性能研究。

(2)含氟光电功能材料的合成、结构与性能;高分子先进功能材料的制备。

(3)利用分子间氢键、全氟烃链憎氟效应(Fluorophobic Effect)稳定金属有机液晶近晶相、盘状液晶六方柱状相。

正承担和已结题科研课题:

1、聚咔唑聚芴盘状高分子液晶的合成与光电性能。

2、液晶模板分子的合成及其主客体超分子建筑。

3、作为有机半导体材料的盘状液晶的分子设计、合成及性能研究。

4、全氟烃链盘状高分子液晶的分子设计、合成及介晶性研究。

5、螺旋型聚乙炔盘状高分子液晶的分子设计、合成及性能。

6、稀土金属有机液晶的合成、结构与介晶性。

7、有机光电子功能材料。

8、有机光电子功能材料产业化关键技术。

9、全氟液晶的合成与开发。

10、以没食子酸为原料的有机半导体材料、高分子功能材料的开发。

11、新型有机发光材料的研制。

12、后过渡金属催化烯烃聚合反应及新材料开发。

13、金属钯催化芳烃偶合反应及在液晶材料合成中的应用。

14、二茂铁金属有机液晶材料的合成及介晶性研究。

15、无尾链金属有机液晶材料的合成及介晶性研究。

国家发明专利:  

已授权国家发明专利

1、赵可清; 杨洋; 余文浩; 汪必琴; 胡平. 2010, 半氟烃链联苯类棒状液晶化合物及其制备方法, 专利号:ZL 201010105054.6

2、赵可清; 孙作鹏; 余文浩; 汪必琴; 胡平. 2009, 侧链含苯并菲盘状液晶基元的聚乙炔及其制备方法, 专利号:ZL 200910167990.7

论文专著:


发表论文:

2013年

1. Bin Han, Ping Hu, Bi-Qin Wang, Carl Redshaw, and Ke-Qing Zhao. Triphenylene discotic liquid crystal trimers
synthesized by Co2(CO)8-catalyzed terminal alkyne [2 + 2 + 2] cycloaddition. Beilstein J. Org. Chem. 2013, 9, 2852-2861. doi:10.3762/bjoc.9.321

2. Wen-Hao Yu, Chao Chen, Ping Hu, Bi-Qin Wang, Carl Redshaw, Ke-Qing Zhao. Tetraphenylethene–triphenylene oligomers with an aggregation-induced emission effect and discotic columnar mesophase. RSC Adv., 2013, 3, 14099-14105. DOI: 10.1039/C3RA41874J.

3. Bo Xiao, Zhao-Jun Liu, Bi-Qin Wang, Ping Hu, Carl Redshaw, Ke-Qing Zhao, Synthesis of Triphenylene Discotic Liquid Crystals Possessing Nine Alkyl Chains: Influence of Molecular Symmetry and Chain Length on Mesomorphism. Mol. Cryst. Liq. Cryst. 2013, 577, 25-35. DOI: 10.1080/15421406.2013.781489.

4. Xue-mei Zhang, Hai-feng Wang, Shuai Wang, Yong-tao Shen, Yan-lian Yang, Ke Deng, Ke-Qing Zhao, Qing-dao Zeng, and
Chen Wang. Triphenylene Substituted Pyrene Derivative: Synthesis and Single Molecule Investigation. J. Phys. Chem. C,
2013, 117, 307-312.

5. Zhen-Qiang Yu, Jacky W. Y. Lam, Ke-Qing Zhao, Cai-Zhen Zhu, Shuang Yang, Jie-Sheng Lin, Bing Shi Li, Jian-Hong Liu, Er-Qiang Chen and Ben Zhong Tang. Mesogen jacketed liquid crystalline polyacetylene containing triphenylene discogen:
synthesis and phase structure. Polym. Chem. 2013, 4, 996-1005. DOI. 10.1039/c2py20535a.

6. Yue-Feng Bai, Long Bao, Ping Hu, Bi-Qin Wang, Carl Redshaw, Ke-Qing Zhao. Copper-free click chemistry between
azides and internal alkynes for triphenylene discotic liquid crystal trimer formation. Liq. Cryst. 2013, 40, 97-105. DOI. 10.1080/02678292.2012.733034.

7. Hai-Liang Ni, Hirosato Monobe, Ping Hu, Bi-Qin Wang, Yo Shimizu, Ke-Qing Zhao. Truxene discotic liquid crystals
with two different ring substituents: synthesis, mesomorphism and high charged carrier mobility. Liq. Cryst. 2013, 40,
411-420. DOI. 10.1080/02678292.2012.755224

8. Yue-Feng Bai, Ke-Qing Zhao, Ping Hu, Bi-Qin Wang and Carl Redshaw. Mono-Disperse Triphenylene Discotic Liquid
Crystal Oligomers Synthesized by Click Chemistry. Current Org. Chem. 2013, 17, 871-885.

9. Hongmei Chen, Ye Liu, Tao Gong, Lin Wang, Keqing Zhao, and Shaobing Zhou. Use of intermolecular hydrogen bonding to synthesize triple-shape memory supermolecular composites. RSC Advances, 2013, 3, 7048.

2012

1. Chun Feng, Xin Wang, Bi-Qin Wang, Ke-Qing Zhao, Ping Hu, Zhang-Jie Shi. One stone two birds: construction of
polysubstituted benzenes from the same starting material and precatalyst by switching the active sites of catalyst with
different additives. Chem. Commun. 2012, 48, 356-358. DOI: 10.1039/clcc15835j.

2. Li Yibao, Zhao Keqing, Yang Yanlian, Deng Ke, Zeng Qingdao, Wang Chen, Functionalization of two-component molecular networks: recongnition of Fe3+, Nanoscale, 2012, 4, 148-151.

3. Hu Li, Ke-Han He, Jia Liu, Bi-Qin Wang, Ke-Qing Zhao, Ping Hu, Zhang-Jie Shi. Straightforward synthesis of
phenanthrenes from styrenes and arenes. Chem. Commun. 2012, 48, 7028-7030.

2011年  

1. H. Monobe, C. Chen, K.-Q. Zhao, P. Hu, Y. Miyake, A. Fujii, M. Ozaki, Y. Shimizu, Bipolar Carrier Transport in Tri-
Substituted Octyloxy-Truxene DLC, Mol. Cryst. Liq. Cryst., 2011, 545: 149-155. DOI: 10.1080/15421406.2011.568891.

2. 赵可清,周慧,余文浩,汪必琴,胡平。钯催化偶联反应合成刚性桥连的苯并菲盘状液晶二聚体,化学学报,2011,69(16),1895-
1902.

3. 赵可清,周慧,余文浩,胡平,汪必琴,物部浩达,清水洋。官能化苯并菲盘状液晶的合成及不饱柔链对介晶性的影响,中国科学:化学,2011,41(10): 1565-1574.

4. ZHAO KeQing, ZHOU Hui, YU WenHao, HU Ping, WANG BiQin, MONOBE Hirosato, SHIMIZU Yo, Synthesis of functionalized
triphenylene discotic liquid crystals and the influence of unsaturated periphery on mesomorphism, Sci.ChinaChem.,2011,54(
10),1576-1583.

5. Li Wang, Xiao-Jun Liu, Ping Huang, Qing-Ping Gong, Yong-Hong Li, Bi-Qin Wang, Ke-Qing Zhao, A New Way to Access
Chiral Liquid Crystals: Organocatalyst-Mediated Synthesis of Chiral Rod-Like Liquid Crystals, Mol. Cryst. Liq. Cryst.,
2011,541,53-59.DOI: 10.1080/15421406.2011.570138

6. K. Q. ZHAO, J. Z. GUO, W. H. YU, L. WANG, P. HU, B. Q. WANG, H. MONOBE, AND Y. SHIMIZU, Synthesis and Mesomorphism of Asymmetric Triphenylene Discotic Liquid Crystals Bearing with Mono-Amido-Based Alkyl Soft Chains. Mol. Cryst. Liq.
Cryst
., 2011,542:37-47.

7. YU-TING LIAO, KE-QING ZHAO, LI WANG, PING HU, AND BI-QIN WANG, Synthesis and Mesomorphism of Novel Chiral
Triphenylene-Based Discotic Liquid Crystals. Mol. Cryst. Liq. Cryst., 2011, 542:75-83.

8. Ke-Qing Zhao, Chao Chen, Hirosato Monobe, Ping Hu, Bi-Qin Wang and YoShimizu. Three-chain truxene discotic liquid
crystal showing high charged carrier mobility. Chem Commun, 2011, 47, 6290-6292.

9. Hong-Mei Chen; Ke-Qing Zhao; Li Wang; Ping Hu; Bi-Qin Wang, Synthesis and Mesomorphism of Triphenylene Discotic
Liquid Crystals Containing Fluorinated Chains, Soft Materials, 2011, 9(4), 359-381.

10.徐丽,赵可清,余文浩,汪必琴,胡平。半氟烃链作桥连的对称酯类二聚体的合成及介晶性, 四川师范大学学报(自然科学版),
2011, 34(1), 95-100. XU Li, ZHAO Ke-Qing, YU Wen-Hao, WANG Bi-Qin, HU Ping, Synthesis and mesomorphism of symmetrical
ester dimer bridged with semi-fluorinated hydrocarbon chain, Journal of Sichuan Normal University(Natural Science), 2011, 34(1), 95-100.

11.Wang L, Gong QP, Liu XJ, Li YH, Huang P, Wang BQ and Zhao KQ, Organocatalyst-mediated Aldol Robinson Cascade
Reactions: A Convenient Synthesis of Substituted Cyclohex-2-enones, Chem. Lett, 2011, 40(2), 138-139.

2010年

1. Li Y, Deng K, Wu X, Lei S, Zhao K, Yang Y, Zeng Q, Wang C. Molecular arrays formed in anisotropically rearranged
supramolecular network with molecular substitutional asymmetry. J. Mater. Chem.,2010,20,9100-9103.

2. Y. Miyake, P. Hu, K.-Q. Zhao, H. Monobe, A. Fujii, M. Ozaki, Y. Shimizu, Carrier mobility behavior of triphenylene mesogen with a hydrogen bonding amide group, Mol. Cryst. Liq. Cryst. 2010,525,97-103.

3. Li Xu, Bi-Jie Li, Zhen-Hua Wu, Xing-Yu Lu, Bing-Tao Guan, Bi-Qin Wang, Ke-Qing Zhao and Zhang-Jie Shi, Nickel-
Catalyzed Efficient and Practical Suzuki−Miyaura Coupling of Alkenyl and Aryl Carbamates with Aryl Boroxines, Org. Lett., 2010, 12 (4), 884–887.

4. 余文浩,聂士常,白跃峰,景阳,汪必琴,胡平,赵可清。点击化学合成盘-棒-盘状液晶三聚体,中国科学: 化学,2010,40(5),467-475.

5. Li-Li Li, Ping Hu, Bi-Qin Wang, Wen-Hao Yu, Yo Shimizu and Ke-Qing Zhao, Synthesis and mesomorphism of ether–ester mixed tail C3-symmetrical truxene discotic liquid crystals, Liquid Crystals, 2010,37(5),499-506.

6. YU WenHao, NIE ShiChang, BAI YueFeng, JING Yang, WANG BiQin, HU Ping, ZHAO KeQing, Synthesis of disk-rod-disk
liquid crystal trimers by using click chemistry, Sci China Chem, 2010,53(5),1134-1141.

7. Hui Zhou, Wen-Hao Yu, Bi-Qin Wang, Ping Hu and Ke-Qing Zhao, Synthesis and mesomorphism of rigid bridge
triphenylene discotic liquid crystal dimmers, Key Engineering Materials Vols. 428-429 (2010) pp 41-46.

8. Yang Yang, Ke-Qing Zhao, Wen-Hao Yu, Bi-Qin Wang and Ping Hu, Synthesis and mesomorphism of semi-fluorinated chain liquid crystals with [1,2,3]-triazole rings, Key Engineering Materials Vols. 428-429(2010) pp 135-139.

9. Qing Yan, Ping Hu, Wen-Hao Yu, Bi-Qin Wang and Ke-Qing Zhao, Synthesis and mesomorphism of 1,1’-disubstitued
ferrocene liquid crystals with a schiff’s base bridge, Key Engineering Materials Vols. 428-429(2010)pp 162-166.

10.Wen-Hao Yu, Yue-Feng Bai, Yang Jing, Shi-Chang Nie, Bi-Qin Wang, Ping Hu and Ke-Qing Zhao, Synthesis of disk-rod-
disk liquid crystal trimers by using click chemistry, Key Engineering Materials Vols. 428-429(2010) pp106-110.

2009

1. 蔡静,曾薇,李权,骆开均,赵可清。8-羟基喹啉过渡金属配合物电子光谱和二阶非线性光学性质,化学学报,2009,67 (20),
2301-2308。

2. 丁涪江,赵可清。含乙烯氧基柔链的苯并菲盘状液晶清亮点的平均场理论研究,化学学报,2009,67 (20),2290-2294。

3. 赵可清,杨高帆,余文浩,汪必琴,胡平。盘状液晶中间体单羟基苯并菲简便合成,有机化学,2009,29(12),2017-2020.

4. Y. F. Bai, K. Q. Zhao, P. Hu, B. Q. Wang, and Y. Shimizu,Synthesis of Amide Group Containing Triphenylene
Derivatives as Discotic Liquid Crystals and Organic Gelators, Mol. Cryst. Liq. Cryst.,2009,509, 60-76.

5. K. Q. Zhao, Y. F. Bai, P. Hu, B. Q. Wang, and Y. Shimizu, Synthesis of Triphenylene Discotic Liquid Crystal Dimers: Click Chemistry As an Efficient Tool, Mol. Cryst. Liq. Cryst., 2009,509,77-88.

6. YANG GaoFan, ZHAO KeQing, YU WenHao, HU Ping, WANG BiQin, Synthesis of unsymmetric triphenylene discotic liquid
crystals with a semi-fluorinated chain and the influence of fluorophobic effect on mesogenic behavior. SciChinaSer B-Chem, 2009, 52(8), 1244-1252.

7. CHEN JunRong, HUANG ChuRui, XU BuYi, LI Quan, ZHAO KeQing, Theoretical study on the charge transport properties of triphenylene discogens with a phenylpropionyloxy or 3-phenylpropenoyloxy side chain. SciChinaSer B-Chem, 2009, 52(8),
1192-1197.

8. Ji Hong, Zhao KeQing, Yu WenHao, Wang BiQin, Hu Ping, Synthesis and mesomorphism of diacetylene-bridged
triphenylene discotic liquid crystal dimers. SciChinaSer B-Chem, 2009, 52(7), 975-985.

9. 黄杵睿,陈俊蓉,徐布一,李权,赵可清。苯丙炔酸和苯丙烯酸酯苯并菲盘状液晶电荷传输的理论研究, 中国科学 B辑: 化学, 2009,39(6),488-494.

10.杨高帆,赵可清,余文浩,胡平,汪必琴。含氟不对称苯并菲盘状液晶的合成及疏氟效应对介晶性的影响, 中国科学 B辑: 化学,2009,39(6),507-517.

11.Biqin Wang, Caiyan Gao, Keqing Zhao, Ping Hu, Synthesis and mesomorphism of mixed ether-ester tail triphenylene
discotic liquid crystals with long alkyloxy peripheral chains, Front. Chem.China, 2009,4(2),177-185.

12.郑述芳,赵可清,余文浩,汪必琴,胡平,新型苯甲酸-吡啶超分子液晶的合成: 全氟烃基和介晶体刚性对液晶性的影响,化学学报,2009,67(8),825-832.

13.Xiaojing Ma, Yibao Li, Xiaohui Qiu, Keqing Zhao, Yanlian Yang and Chen Wang, Two-dimensional rigid molecular
network with elastic boundaries for constructing hybrid molecular assemblies, J. Mater. Chem. 2009,19,1490-1493.

14.赵可清,余文浩,汪必琴,胡平,氢键稳定的含酰胺基的盘状液晶研究进展,四川师范大学学报(自然科学版),2009,32(1),
118-133.

15.Ma X.; Yang Y.; Wang C.; Zhao K. Molecular absorptive behavior of liquid crystal molecular templates, J. Nanosci. Nanotechnol. 2009, 9(2), 1148-1151.

2008年

1. Lam JWY, Xing C, Zhao K, Tang BZ, Discotic liquid crystals: synthesis and mesomorphic properties of polyacetylenes
carrying triphenylene pendant groups, Proc. of SPIE, 2008, 7050, 70500M. (Invited Paper)

2. 冀虹,赵可清,余文浩,汪必琴,胡平。二乙炔桥连苯并菲盘状液晶二聚体的合成及其介晶性,中国科学 B辑: 化学,2008,38(
12),1088-1099.

3. 陈先凯,陈俊蓉,李权,赵可清。对苯二甲酸二苯酯类液晶化合物的光谱和二阶非线性光学性质的理论研究,有机化学,2008,28(6),1050-1054.

4. 简忠保,赵可清,胡平,汪必琴。不对称苯并菲盘状液晶的合成及取代基对介晶性的影响,化学学报, 2008,66(11),1353-1360.

5. 宋质琼,赵可清,胡平,汪必琴。有玻璃态和液晶态的胆甾烯基苯并菲的合成及介晶性,化学学报,2008,66(11),1344-1352.

6. Wang Bi-Qin, Xiang Shi-Kai, Sun Zuo-Peng, Guan Bing-Tao, Hu Ping, Zhao Ke-Qing, Shi Zhang-Jie, Benzylation of
arenes through FeCl3-catalyzed Friedel-Crafts reaction via C-O activation of benzyl ether, Tetrahedron Letters, 2008,49,4310-4312.

7. Li Min, Yang Yan-Lian, Zhao Ke-Qing, Zeng Qing-Dao, Wang Chen, Bipyridine-mediated assembling characteristics of
aromatic acid derivatives, J. Phys. Chem. C 2008,112, 10141-10144.

8. Ma, X.; Yang, Y.; Deng, K.; Zeng, Q.; Zhao, K.; Wang, C.; Bai, C. Molecular miscibility characteristics of self-
assembled 2D molecular architectures, J. Mater. Chem. 2008, 18, 2074-2081.

9. 孙定光,丁涪江,赵可清。含酯基和酰胺基支链的苯并菲液晶电荷传输性质的量子化学研究,化学学报,2008,66(7),738-744.

10.汪必琴,丁涪江,赵可清。用平均场理论研究盘状液晶分子间氢键对清亮点的影响,化学学报,2008,66(6),627-632.

11.Xing, C.; Lam, J. W. Y.; Zhao, K.; Tang, B. Z., Synthesis and liquid crystalline properties of poly(1-alkyne)s
carrying triphenylene discogens, J. Polym. Sci. Part A: Polym. Chem., 2008,46,2960-2974.

12.Quan LI, Jing CAI, Jun-Rong CHEN, Ke-Qing Zhao, Density Functional Theory Study of Red-shifted Hydrogen Bonds of 4-Pyridinemethanol with Water, Chin. J. Chem. 2008,26(2);255-259.

13.Guan, B.-T.; Xiang, S.-K.; Wu, T.; Sun, Z.-P.; Wang, B.-Q.; Zhao, K.-Q.; Shi, Z.-J. Methylation of arenas via Ni-catalyzed aryl C-O/F activation, Chem Commun. 2008,1437-1439.

14.Guan, B.-T.; Xiang, S.-K.; Wang, B.-Q.; Sun, Z.-P.; Wang, Y.; Zhao, K.-Q.; Shi, Z.-J. Direct benzylic alkylation via Ni-
catalyzed selective benzylic sp3 C-O activation, J. Am. Chem. Soc. 2008,130,3268-3269.

15.陈俊蓉,蔡静,李权,赵可清。二甲基乙酰胺与醇分子间相互作用的理论研究,化学学报,2008,66(5),536-540.

2007年

1. Ma, X.-J.; Yang, Y.-L.; Deng, K.; Zeng, Q.-D.; Wang, C.; Zhao, K.-Q.; Hu, P.; Wang, B.-Q. Identification of a
peripheral substitution symmetry effect in self-assembled architectures, ChemPhysChem, 2007,8,2615-2620.

2. 汪必琴,余文浩,赵可清,胡平,丙基联苯酯型液晶的合成: 不饱和端基及氧原子对介晶性的影响,化学研究与应用,2007,19(
11),1215-1222.

3. Wang, B. Q.; Zhao, K. Q.; Hu, P.; Yu, W. H.; Gao, C. Y.; Shimizu, Y. Tuning hydrogen-bonding with amide groups for stable columnar mesophases of triphenylene discogens, Mol. Cryst. Liq. Cryst. 2007,479,135-150.

4. 汪必琴,简忠保,赵可清,余文浩,胡平。含亚胺和胆甾烯基不对称液晶二聚体的合成及介晶性,化学学报,2007,65(22),
2570-2576.

5. 汪必琴,雷柏林,杨高帆,赵可清,余文浩,胡平,丁涪江。苯丙炔酸和苯丙烯酸酯苯并菲盘状液晶的合成及介晶性,有机化学
2007,27(12),1552-1557.

6. 汪必琴,王新玲,赵可清,胡平。含全氟烃基的联苯酯类液晶的合成及其介晶性,化学学报,2007,65(21),2499-2504.

7. 汪必琴,高彩艳,赵可清,胡平。含有长烷氧链混合醚-酯类苯并菲盘状液晶的合成及其介晶性研究,化学研究与应用,2007,19(10),1102-1111.

8. 丁涪江,汪必琴,赵可清。用平均场近似研究液晶分子结构与清亮点的关系,化学学报,2007,65(20),2224-2228.

9. 胡競丹,李权,赵可清。 羟基取代苯并菲化合物分子的结构与电荷传输性质研究,化学学报,2007,65(17),1784-1788.

10.Li Quan, Hu Jing-Dan, Zhao Ke-Qing, DFT study of hydrogen-bonded 1,3,5-triazine-water complexes, Chin. J. Chem. 2007, 25, 1078-1081.

11.陈红梅,赵可清,胡平,汪必琴。半氟烃链苯并菲盘状液晶的合成及其介晶性,化学学报,2007,65(14),1368-1376.

12.丁涪江,赵可清。分子间氢键对苯并菲柱状介晶相的影响:量子化学ONIOM(MO/MM)研究,化学学报,2007, 65(15),1454-1458.

13.余文浩,赵可清,汪必琴,胡平。氢键稳定的苯并菲盘状液晶的合成及介晶性,化学学报,2007, 65(12),1140-1148.

14.李辉容,胡平,汪必琴,赵可清。含氧亚甲基联苯液晶的合成及介晶性,四川师范大学学报(自然科学版),2007, 30(2), 223-227.

15.丁涪江,赵可清。适用于液晶大分子的量子化学计算方法以及六烷氧基苯并菲取代的1,3,5-三酰胺苯液晶的研究,化学学报,2007, 65(8), 660-666.

16.刘焕英,胡競丹,李权,赵可清。苯乙烯基吡啶类化合物几何结构与光谱的理论研究,有机化学, 2007, 27(4), 507-512.

17.Zhao Ke-Qing, Hu Ping, Wang Bi-Qin, Yu Wen-Hao, Chen, Hong-Mei, Wang Xin-Ling, Shimizu Yo, Synthesis of Mixed Tail Triphenylene Discotic Liquid Crystals: Molecular Symmetry and Oxygen-Atom Effect on the Stabilization of Columnar
Mesophases, Chin. J. Chem. 2007, 25, 375-381.

2006年

1. Zhao, K.-Q.; Wang, B.-Q.; Hu, P.; Gao, C.-Y.; Yuan, F.-J.; Li, H.-R. New triphenylene based discotic liquid
crystals with mixed tails: molecular symmetry and wide columnar mesophase range, Chin. J. Chem. 2006, 24, 210-214.

2. 赵可清,高彩艳,胡平,汪必琴,李权。含有酯基及酰胺基柔链的苯并菲盘状液晶的合成、分子间氢键对柱状介晶性的影响,化学学报,2006,64(10),1051-1062.

3. 高彩艳,赵可清,汪必琴,胡平。含氧亚甲基中心桥键席夫碱型液晶化合物的合成及介晶性,化学学报, 2006,64(8),743-750.

4. FU-JIANG DING, YUN-QING HE, KE-QING ZHAO, Extrapolation of the Linear and Nonlinear Polarizabilities From Ab Initio Finite Oligomer Calculations, International Journal of Quantum Chemistry, 2006, 106, 1934-1942.

5. 丁涪江,赵可清。某些电荷转移反应中线性反应坐标确定的反应途径的非唯一性,化学学报,2006,64(2),117-120.

6. 何云清,丁涪江,赵可清。端基取代的长链硅烷二阶超极化率的量子化学研究, 化学学报,2006,64,799-805.

7. 丁涪江,赵可清。平面四方金属苯配合物的二阶超极化率的量子化学计算,化学学报,2006,64(19),2003-2007.

8. 丁涪江,赵可清。环聚炔苯和环聚炔吡啶组成的盘状液晶中的电荷转移,物理化学学报,2006,22(6),764-767.

9. 黄方千,李权,赵可清。 s-四嗪-水簇复合物的理论研究,化学学报,2006,64(16),1642-1648.

10.Li Quan, Huang Fang-qian, Hu Jing-dan, Zhao Ke-qing, Hydrogen-bonding interaction of 1,2,3-triazine-waters
complexes, 化学物理学报,2006, 19(5): 401-405.

11.李权,黄方千,胡競丹, 赵可清。 A theoretical study on the Structures and Properties of the Hydrogen Bonding
Complexes Between Diazines and Water,中国化学 2006,24(12): 1700-1703.

12.Li Yun-Chun, Li Quan, Zhao Ke-Qing, A computational study of hydrogen bonding complexes between 1,2,3-triazine and water, J. Mol. Struct.(Theochem.), 2006, 766: 83-86.

13.李权,胡競丹,黄方千,赵可清。新型含氧亚甲基和亚胺桥键液晶化合物分子结构与光谱的密度泛函理论研究,原子与分子物理学报,2006,23(6): 1034-1038.

2005年

1. 赵可清, 胡平,汪必琴,许洪波,李权,张良辅。新型含氧亚甲基和亚胺桥键的液晶化合物的合成及介晶性,化学学报,2005,63(5),427-433.

2. ZHAO, Ke-Qing, WANG, Bi-Qin, HU, Ping, LI, Quan, ZHANG, Liang-Fu, Synthesis of New Triphenylene-containing Discotic Liquid Crystals and the Influence of Fluorophilic Effect and Molecular Symmetry on Mesomorphism, Chin. J. Chem., 2005, 23, 767-774.

3. 丁涪江,何云清,刘柳斜,赵可清。平面四方金属苯配合物的非线性光学性质的从头算研究,化学学报,2005,63(24),2199-2204.

4. 丁涪江,何云清,赵可清,长链分子超极化率的单元平均值和差分值的不同渐近性质,化学学报,2005,63(18),1747-1752.

2003年

1. Guang, W.; Han, J.; Wan, W.; Zhao, K.; Zhang, L., synthesis and liquid crystal properties of dinuclear
cyclopalladated 5-alkyl-2-(4’-alkoxyphenyl)pyrimidine and 3-(4’-alkoxyphenyl)-6-alkoxypyridazine complexes, Liq. Cryst. 2003, 30(11), 1259-1265.

国际国内邀请报告、口头报告、国际学术会议论文等:

2013

1. Ke-Qing Zhao, Ping Hu, Bi-Qin Wang, Discotic Liquid Crystalline Semiconductors: Molecular Designing, Synthesis, and Physical Properties. The 2nd SLCP, Chengdu,China. April 19-24, 2013.

2. Wen-Hao Yu, Yan-Hong Wang, Jiang-Ze Guo, Bi-Qin Wang, Ping Hu, Ke-Qing Zhao. Triphenylene Discotic Liquid Crystal
Dimers Anchored with Hydrogen Bonding and Perfluorinated Chains. The 2nd SLCP,Chengdu,China. April 19-24, 2013.

3. Bo Xiao, Chao Chen, Xiao-Yan Bai, Wen-Hao Yu, Bi-Qin Wang, Ping Hu, Ke-Qing Zhao. Three-Chain Truxene and Truxenone Discotic Liquid Crystals: Synthesis and Polymorphism. The 2nd SLCP,Chengdu,China. April 19-24, 2013.

4. Qiu-Bing Lv, Yong-Hong Li, Ping Hu, Bi-Qin Wang, Ke-Qing Zhao. Synthesis and Mesomorphism of 2,6,10-Triphenylenetricarboxamides with Linear and Branched Alkyl Substituents. The 2nd SLCP,Chengdu,China. April 19-24, 2013.

5. Bin Han, Ping Hu, Bi-Qin Wang, Ke-Qing Zhao. Synthesis of Star-Shaped Triphenylene Discotic Liquid Crystal Trimers by Using Co2(CO)8 Catalyzed Terminal Alkynes [2+2+2] Cycloaddition. The 2nd SLCP,Chengdu,China. April 19-24, 2013.

6. 肖波, 胡平, 汪必琴, 赵可清. 盘状液晶半导体材料自组装有序结构研究. 中国物理学会(CPS)2013秋季学术会议. 2013.9.12-9.15.中国 厦门.

2012

1.冯春,汪欣,汪必琴,赵可清,胡平,施章杰. Grubbs催化剂参与的多取代苯的合成研究, 06-P-072. 中国化学会第28届学术年会,(28th CCS Congress), 2012年4月13-16日,四川成都。

2.袁玥,胡平,余文浩,汪必琴,赵可清. 点击反应合成吐昔烯-苯并菲盘状液晶齐聚物, 05-P-059. 中国化学会第28届学术年会,(28th CCS Congress), 2012年4月13-16日,四川成都。

3.王海峰,胡平,汪必琴,赵可清. 基于苯并菲的三芳胺类蓝光材料的合成及其光学性质研究, 15-P-096. 中国化学会第28届学术年会,(28th CCS Congress), 2012年4月13-16日,四川成都。

4.胡平, 陈超,魏晓丽,余文浩,汪必琴,赵可清. 具有聚集诱导发光效应的四苯基乙烯-苯并菲多聚体, 15-P-100. 中国化学会第28届学术年会,(28th CCS Congress), 2012年4月13-16日,四川成都。

5.刘兆军,汪必琴,胡平,赵可清. 咔唑-苯并菲盘状液晶多聚体, 15-I-040. 中国化学会第28届学术年会,(28th CCS Congress), 2012年4月13-16日,四川成都。

6.余文浩,郭江泽,汪必琴,胡平,赵可清. 氢键和全氟烃链锚定苯并菲盘状液晶柱状相, 15-P-095. 中国化学会第28届学术年会,(28th CCS Congress), 2012年4月13-16日,四川成都。

7.胡平,倪海亮,汪必琴,赵可清. 吐昔烯酮-苯并菲盘状液晶齐聚物的合成及介晶性, 05-P-057. 中国化学会第28届学术年会,(28th CCS Congress), 2012年4月13-16日,四川成都。

8.白跃峰,胡平,汪必琴,赵可清. 无铜点击合成新型非C3轴对称苯并菲盘状液晶三聚体及其介晶性研究, 05-P-056.中国化学会第28届学术年会,(28th CCS Congress), 2012年4月13-16日,四川成都。

9.H. Ni, H. Monobe, P. Hu, B. Wang, Y. Shimizu, and K. Zhao. Semiconducting Truxene Discotic Liquid Crystals:
Synthesis, Mesomorphism, and High Charged Carrier Mobility. Oral presentation. 24th International Liquid Crystal Conference,Mainz, 19-24 August, 2012.

10. Zhao-Jun Liu, Ping Hu, Bo Xiao, Yan-Hong Wang, Bi-Qin Wang, Ke-Qing Zhao. Blue Light-Emitting Carbazole
Derivatives with Triphenylene Discogen and Cholesterol Moiety. PII-176. 24th International Liquid Crystal Conference,Mainz, 19-24 August, 2012.

11. Cao Chen, Hong-Bo Xu, Xiao-Li Wei, Wen-Hao Yu, Ping Hu, Ke-Qing Zhao.Synthesis of Tetraphenylethene-Triphenylene
Oligomers by Click Chemistry and Their Aggregation-Induced Emission Effect. PI-072. 24th International Liquid Crystal Conference,Mainz, 19-24 August, 2012.

12. B. Xiao, H.-L. Ni, C. Chen, H. Monobe, P. Hu, B.-Q. Wang, Y. Shimizu, K.-Q. Zhao. New Truxene and Truxenone DLCs: Synthesis, Mesomorphism, And Charge Carrier Mobility. The 1st Asian Conference on Liquid Crystals, 16-18 Dec 2012.Yamanashi,Japan.

2011年

1. 赵可清,张晓波,何科翰,刘兆军,胡平,王必琴,金属催化偶联反应在液晶半导体材料合成中的应用,O-37, 第十二届全国均相催化学术会议,四川 成都,2011, 10.

2. 赵可清, 陈超, 倪海亮, 胡平, 汪必琴, 盘状液晶半导体化合物的合成与电荷传输性质, 中国物理学会2011年秋季学术会议, 浙江大学, 2011年9月15日-18日.

3. Ke-Qing Zhao, Ping HU, Bi-Qin WANG, Hirosato MONOBE, YoSHIMIZU, Pyrene-Cored Triphenylene and Cholesterol Liquid
Crystalline Oligomers: Synthesis and Physical Properties, The 5th East Asia Symposium on Functional Dyes & Advanced Materials,Hangzhou,China, September 26-29, 2011.

2010年

1. Ke-Qing Zhao, Xiao-Bo Zhang, Wen-Hao Yu, Li Wang, Ping Hu, Bi-Qin Wang, Hirosato Monobe, Yo Shimizu, Synthesis and Mesomorphism of Hydrogen Bonded Triphenylene Discotic Liquid Crystals and Oligomers, O5, 23rd International Liquid Crystal
Conference, July 11th – 16th, 2010, Krakow, Poland.

2. Ke-Qing Zhao, Xiao-Bo Zhang, Li Wang, Bi-Qin Wang, Ping Hu, Hirosato Monobe, Yo Shimizu, Synthesis and Liquid
Crystalline Properties of New Triphenylene Discotic Oligomers, P-1. 80, 23rd International Liquid Crystal Conference, July 11th – 16th, 2010,Krakow,Poland.

3. Wang Li, Liu Xiaojun, Huang Ping, Gong Qingping, Li Yonghong, Zhao Keqing, Organocatalyst-Mediated Synthesis of
Chiral Rod-Like Liquid Crystals and Mesogens with Enone Functionalities: A New Way to Access Chiral Liquid Crystals, P-1. 79, 23rd International Liquid Crystal Conference, July 11th – 16th, 2010,Krakow,Poland.

4. Yasuo Miyake, Hirosato Monobe, Ping Hu, Ke-Qing Zhao, Akihoko Fujii, Masanori Ozaki, Yo Shimizu, Mesomorphism and
carrier transport property of alkylester substituted perylenes. P-1. 47, 23rd International Liquid Crystal Conference, July 11th – 16th , 2010,Krakow,Poland.

5. Hirosato Monobe, Chao Chen, Ke-Qing Zhao, Ping Hu, Yasuo Miyake, Akihiko Fujii, Masanori Ozaki, Yo Shimizu, Bipolar carrier transport in tri-substituted octyloxy-truxene DLC. P-1. 204, 23rd International Liquid Crystal Conference, July 11th – 16th, 2010,Krakow,Poland.

2009年

1. 赵可清, 孙作鹏, 余文浩, 汪必琴, 胡平, 含苯并菲介晶基元的聚乙炔盘状液晶的合成与性质, E-O-06, 2009年全国高分子学术论文报告会, 8月18日-22日, 2009. 中国,天津.

2.  Carrier mobility behavior of a triphenylene mesogen with hydrogen bonding interactions of the amide groups.Y.
Miyake, P. Hu, K.-Q. Zhao, Hi. Monobe, A. Fujii, M. Ozaki, Y. Shimizu. 2009 International Symposium on Liquid Crystal Science and Technology (ISLCST 2009). August 2-5, 2009,Kunming,China.

3. Synthesis and mesomorphism of rigid bridge triphenylene discotic liquid crystal dimers. H. Zhou, W.-H. Yu, B.-Q.
Wang, P. Hu, K.-Q. Zhao. 2009 International Symposium on Liquid Crystal Science and Technology (ISLCST 2009), August 2-5, 2009,Kunming,China. (Invited talk)

4. Synthesis and mesomorphism of 1,1'-disubstituted ferrocene liquid crystals with a Schiff's base bridge. Q. Yan,
P. Hu, W.-H. Yu, B.-Q. Wang, K.-Q. Zhao, 2009 International Symposium on Liquid Crystal Science and Technology (ISLCST 2009), August 2-5, 2009,Kunming,China.

5. Synthesis and mesomorphism of semi-fluorinated chain liquid crystals with 1,4-disubstituted 1,2,3-triazole ring.
Y. Yang, W.-H. Yu, B.-Q. Wang, P. Hu, K.-Q. Zhao. 2009 International Symposium on Liquid Crystal Science and Technology (ISLCST 2009), August 2-5, 2009,Kunming,China.

6.  Synthesis and properties of poly(1-alkyne)s rod-like liquid crystals containing fluorinated chain, P. Kang, W.-H. Yu, P. Hu, B.-Q. Wang, K.-Q. Zhao. 2009 International Symposium on Liquid Crystal Science and Technology (ISLCST 2009). August 2-5, 2009,Kunming,China.

7. Zhao KQ, Bai YF, Hu P, Wang BQ, Shimizu Y, Synthesis and mesomorphism of star-shaped discotic liquid crystals by
copper-catalyzed azide-alkyne cycloaddition, The 4th  East Asia symposium on Functional Dyes and Advanced Materials, EAS4, June 2-5, 2009, International House, Osaka, Japan (Invited Lecture).

8.  Miyake Y, Hu P, Zhao KQ, Monobe H, Fujii A, Ozaki M, Shimizu Y, Carrier mobility in stable columnar mesophase of
triphenylene with hydrogen bonding interaction of the amido group, The 4th East Asia symposium on Functional Dyes and Advanced Materials, EAS4, June 2-5, 2009, International House, Osaka, Japan.

2008年

1, Zhao, KQ, Bai, YF, Hu P, Wang, BQ,Shimizu, Y. Synthesis of triphenylene discotic liquid crystal dimers, oligomers
and polymers: click chemistry as an efficient tool, The 22nd International Liquid Crystal Conference, Poster 3-MA16, June 29-July 4, 2008, ICC Jeju,Jeju,Korea.

2, Zhao, KQ, Bai, YF, Hu P, Wang, BQ, Shimizu, Y. Synthesis of amide group containing triphenylene derivatives as
discotic liquid crystals and organic gelators, The 22nd International Liquid Crystal Conference, Poster 3-MA15, June 29-July 4, 2008, ICC Jeju, Jeju, Korea.

3, Miyake, Y.; Monobe, H.; Yu, WH, Zhao KQ,Shimizu, Y. Liquid crystalline semiconductors of triphenylenes: hydrogen
bond controlled carrier mobility, The 22nd International Liquid Crystal Conference, Poster 3-MA52, June 29-July 4, 2008, ICC Jeju,Jeju,Korea.

2007年及以前

1. K. Q. Zhao, P. Hu, B. Q. Wang, C. Y. Gao, W, H. Yu, Y. Shimizu, Mixed tail triphenylene discogens with ester or
amide groups: The effect of hydrogen bonding on mesomorphism, SYNT1-O3, p50, Abstracts, 21st International Liquid Crystal Conference, Keystone, Colorado, USA, July 2–7, 2006.

2. B. Q. Wang, K. Q. Zhao, P. Hu, X. L. Wang, Synthesis and liquid crystal properties of ferrocene-containing
triphenylene based discotic metallomesogens, SYNTP-73, p343, Abstracts, 21st International Liquid Crystal Conference, Keystone, Colorado, USA, July 2–7, 2006.

3. B. Q. Wang, K. Q. Zhao, P. Hu, H. M. Chen, Synthesis and self-assembly behavior of large triphenylene based
discotic liquid crystals, SYNTP-74, p344, Abstracts, 21st International Liquid Crystal Conference, Keystone, Colorado, USA, July 2–7, 2006.

4.  Xing, C. M.; Zhao, K. Q.; Lam, J. W. Y.; Tang, B. Z. Synthesis and Discotic Liquid Crystalline Polyacetylenes with triphenylene-Cored Mesogenic Pendants, Polymer Preprints, 2006, 47(2), 687-688.

5. Okada, K.; Zhao, K.-Q.; Monobe, H.; Terasawa, N.; Shimizu, Y., Carrier mobility of the novel triphenylene-based
discotic liquid crystal compounds with the polymerizable functional groups, Japanese Liquid Crystal Society, 2A03, 134, 2004.

6. Hori, H.; Monobe, H.; Okada, K.; Zhao, K.-Q.; Terasawa, N.; Awazu, K.; Shimizu, Y., Alignment change of
triphenylene derivative discotic liquid crystal with polymerizable functional groups by infrared irradiation, Japanese Liquid Crystal, PB26, 380, 2004.

7. Hori, H.; Monobe, H.; Okada, K.; Zhao, K. Q., Shimizu, Y. Preparation of a polymer film by photopolymerization of
the alignment controlled domains of Colh mesophase by polarized infrared technique, Japanese Liquid Crystal Society, 2005, 2B07。

8. 宋质琼,赵可清,汪必琴,胡平,玻璃态和液晶态结构的胆甾烯基苯并菲,2007年全国高分子学术论文报告会,E-P-198。

9. 赵可清,孙作鹏,简忠保,刘向阳,顾宜,侧链含棒状液晶基元的聚酰亚胺的合成及性质,2007年全国高分子学术论文报告会,E-P-189.

荣誉奖励:


1、四川师范大学第三届首席教授(2013)。

2、国务院政府特殊津贴(2012)。

3、第九批四川省有突出贡献的优秀专家(2010)。

4、四川省劳动模范(2010年)。

5、四川省科学技术进步奖三等奖:有机液晶材料的分子设计、合成、性能,以及构效关系的量子化学研究(2009年)。

6、成都市科学技术进步奖二等奖:有机液晶材料的分子设计、合成、性能,以及构效关系的量子化学研究(2009年)。

7、四川省科技进步三等奖:VIP受体介导放射性反义显象和反义治疗研究 (与华西医院合作)(2006年)。

8、四川省学术与技术带头人后备人选。

9、四川省“杰出青年培养基金”获得者。

10、2001年获国家留学基金资助。

实验室项目合作:


课题组已完成有如下机半导体化合物定制合成(联系电话:136 9906 7543。E-mail: kqzhao@sicnu.edu.cn.)。

苯并菲,Triphenylene (99%), CAS No. [217-59-4],

十二氢苯并菲,CAS No. [1610-39-5].

六溴苯并菲,hexabromotriphenylene CAS No. [82632-80-2]

Hexamethoxytriphenylene CAS No. [808-57-1]

Hexaacetoxytriphenylene CAS No. [32829-08-6]

2,3,6,7,10,11-hexahydroxytriphenylene, C18H6(OH)6; CAS No. [4877-80-9]

2,3,6,7,10,11-hexaalkoxytriphenylene, C18H6(OR)6, R = C4H9 - C16H33;

CAS NO. [70351-84-7], C3O-TP

CAS NO. [70351-85-8], C4O-TP

CAS NO. [69079-52-3], C5O-TP

CAS NO. [70351-86-9], C6O-TP

CAS NO. [69079-53-4], C7O-TP

CAS NO. [70351-87-0], C8O-TP

CAS NO. [70351-89-2], C10O-TP

Monohydroxy-triphenylene:

2-hydroxy-3,6,7,10,11-pentaalkoxytriphenylene, C18H6(OR)5(OH), R = C4H9 to C16H33 trihydroxytriphenylenes:

2,6,10-trihydroxy-3,7,10-trialkoxytriphenylene, sym-C18H6(OR)3(OH)3;

CAS No. [168847-20-9], C5 CAS No. [227024-10-4], C6

2,6,11-trihydroxy-3,7,10-trialkoxytriphenylene, asym-C18H6(OR)3(OH)3; 2,7-triphenylene-diol: C5, CAS NO [102737-76-8]。

C6, CAS NO [160257-87-4]。

Triphenylene-2-boronic acid neopentyl glycol ester, 99%。

Triphenylene-2-boronic acid pinacol ester, 99%。

1-bromopyrene, CAS No. [1714-29-0]。

1,6-dibromopyrene, CAS No [27973-29-1]。

1,3,6,8-Tetrabromopyrene, CAS No. [128-63-2]。

hexaphenylbenzene, CAS No [992-04-1]。

hexakis(4-bromophenyl)benzene, CAS No [19057-50-2]。

2,3,6,7,10,11-hexabromo-triphenylene CAS No [82632-80-2]。

triphenylene-2-boronic acid。

Hexabenzocoronene。

2-bromo-triphenylene, CAS NO [19111-87-6]。

1,3,6,8-Tetrabromocarbazole, CAS No [55119-09-0]。

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