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徐 正 男 教授 博士生导师。1962年毕业于南京大学化学系,1966年研究生毕业于中科院大连化学物理研究所。研究生期间从事高温快速反应动力学和化学激光研究;1968-1980年围绕着二机部的任务,开展新材料研制,解决了核材料的存贮问题,受到国防科委嘉奖和全国科学大会奖;1981年至今从事配位化学、纳米化学、富勒烯化学的基础研究。作为访问教授曾多次去加拿大、意大利和德国进行合作研究:1988-1990年 Guelph 大学和Concordia大学、1993年、1997年Guelph大学,1999年Western Ontario大学,2009年德国莱比锡大学、Max Planck界面和胶体研究所、意大利帕玛大学等。曾承担国家自然科学基金会重点项目,重大项目子项目,参与重大项目研究工作,主持江苏省自然科学基金会重点项目的研究。科研成果曾获国家自然科学三等奖,国家教委科技进步一等奖和二等奖,2004教育部提名国家科学技术奖自然科学一等奖。发表科学论文300多篇, 6篇论文被选为热点论文。论文被他引2000多次。获授权专利7项,出版专著一部。指导的一位研究生的博士论文入选全国优秀博士论文。主要成就如下:

一. 纳米化学

对纳米晶可控合成和有序组装进行了系统的研究,建立了 “固液相合成方法”,实现了金属纳米粒子的大小可控,得到了不同尺度的纳米晶和二维、三维超晶格。调控反应的动力学和热力学控制区,实现纳米粒子相结构的调控。与“热注入法” 相比,该方法不需用昂贵和有毒的有机金属化合物,仅用价廉的无机盐固体。建立了“智能” 胶体体系实现了溶液中半导体纳米晶的一维外延生长。不需先制备晶种,体系会自动调节晶种和外延物种生成的时间,并产生与外延物种匹配的晶面,以调控外延半导体的相结构。他们在限制空间内构筑了聚合物纳米粒子的有序阵列,论文被选为Hot paper。

把化学上不同的物种组合成一个区域组分可分的纳米粒子是开发新功能材料的有效途径, 因为异质界面间的强作用会产生新颖的性质。轴向异质复合结构的构筑较为困难,通常先制备纳米线,后在纳米线上外延生长第二种物种。他们则采用相反的方法,先制备壳,然后在壳内构筑第二种物种,构成轴向异质核壳结构。建立了二级模板法,构筑了一系列轴向异质复合结构有序阵列,把纳米粒子的可控合成和有序组装在一步中完成。研究了它们的微结构、磁性和场发射性能等,与国际同类工作相比,具有金属纳米线连续完整、纳米管填充率高等优点,处于国际先进行列。

聚合物/金属轴向异质复合结构有效地保护了金属纳米线免受大气的侵蚀,使纳米结构性能稳定。论文已被他引一百多次。Niu 和 Chen 等对此工作的评价为:“用导电聚合物包覆的具有光、电、磁特性的无机纳米棒结构提供了一个令人振奋的体系,此体系可用来探索设计功能器件的可能性,因为纳米同轴核壳结构常常显示出与单纯的核和壳不一样的物理和化学性质。”金属Co和Ni纳米管有序阵列的论文已被他引132次。第三世界科学院院长Rao在他的论文中详细介绍了这项工作,并指出: “这是迄今为止已合成出的少数几种金属纳米管之一。” Dai 等指出:“徐等制备了高度有序的磁性Ni纳米管阵列,长达35 μm,纳米管具有增强的矫顽力,有可能在信息存储等领域取得应用” ;用溶胶-凝胶法构筑了一系列金属氧化物 (硫化物) /金属轴向复合结构有序阵列,金属纳米线有利于半导体光激发电子的存贮,改善了半导体的光电性能;用一步法构筑了碳纳米管/ZnS和CdS单晶纳米线轴向异质复合结构,长达十几微米。在碳纳米管中组装Ni纳米管构成新颖的管中管结构有序阵列,论文被该杂志选为Top Ten Most Accessed Article;他们在碳纳米管内组装了长达50 μm的金属纳米线。填充率几乎达100%。国际纳米网站 nanotechweb.org 详细介绍了这项工作,并指出:“南京大学的研究工作者已经用二级模板法在碳纳米管中填装了金属Co和Ni,该技术可用于制造纳电子器件、高密度磁记忆器件、电化学能量储存和传感器等”;Jin的评价为:“将金属纳米粒子填入碳管后将会改变碳管的电子结构,因此通过改变金属纳米粒子的大小和浓度,能够调控碳纳米管的电子性质。这类新颖的复合结构不仅对于研究碳管和金属粒子之间的相互作用具有重要的学术意义,而且对于催化、电、磁器件等应用也十分重要”;系统研究了乳液,微乳液和多重乳液反应体系的物理和化学性质,在液相中构筑了磁性金属亚微米和纳米空心球,超结构显示出新颖的磁性质,两篇论文均被选为 Top Ten Most Accessed Articles,还被 “Small” 杂志作为 highlights 论文介绍;发现 ZnO 纳米管有序阵列具有优良的场发射性能,论文被选为Hot paper;用建立的固液相反应路线,成功地构筑了过渡金属氧化物,稀土氧化物的单晶纳米带;对纳米粒子的催化作用进行了深入研究,发现了一例非金属催化剂,该催化剂对硝基苯衍生物催化加氢制苯胺衍生物有极高的活性和选择性;用小分子组装得到了智能有机凝胶和有机超分子微管,凝胶对pH值高度敏感,可用pH可逆地调控溶胶/凝胶的转变和粘弹力。这些工作都富有创新性。

二.富勒烯化学和物理

系统地研究了富勒烯的化学反应。建立了选择性合成C60、C70负离子水溶液和水溶胶的有效方法,为富勒烯在生物体中的应用和构筑纳米结构创造了条件;用Sol-gel法构筑了C60和C70 纳米管(线)有序阵列,进而构筑了C60和C70纳米管/金属Ni纳米线轴向异质复合结构有序阵列。受到了国内外同行的广泛关注。Scott等采用了此选择性还原方法,成功地在大量稠环芳烃混合物中检测到了微量的C60,避免了繁复的分离和提纯,证明了C60分子全合成的成功。朱道本教授等的评价为:“南京大学对C60、C70的还原反应进行了系统的研究,发现在酸性条件下,用化学还原生成富勒烯氢化物,但在碱性条件下则生成富勒烯负离子。文献报道富勒烯负离子对水敏感,而在南京大学的实验室中发现,C60n-、C70n-在无氧存在时对水并不敏感。更有意义的是,在国际上首次发现无需控制还原剂的化学计量,只要改变溶剂,就能定量生成C60- 离子的水溶液。”

三.金属配合物的研究:

对稀土金属配合物进行了系统研究,发现了一些新反应和新方法工作被 Edelmann 等广泛引用;开展了多核配合物的研究,较早合成出Mn11Cr单分子磁体(SMM)。Chakov等指出此合成方法是目前用Mn12前体合成SMM的两条主要路线之一。

科学研究:

研究方向:

1.纳米化学:大小、形状和相结构可控的纳米粒子的制备;纳米线、纳米管及纳米复合结构有序阵列的制备、结构和性质

2. 纳米材料合成中的配位化学

在研项目:

重大研发计划:形状化纳米晶的可控合成,组装和形状相关性质的研究

973项目子课题:半导体纳米线结构设计,可控制备及机理

合作研究:

1. 加拿大 International Scientific Exchange Award 作为访问教授赴加拿大 Guelph 大学和 Concordia 大学进行二年合作

2. 1993年7月和1997年8月受 Guelph 大学邀请作为访问教授进行短期合作科研

3. 1999年7月受 Western Ontario 大学 CenPhysics 的邀请,作短期合作科研

4. 2008年10-11月受德国MPI胶体和界面研究所,Leipzig大学,意大利 Parma 大学的邀请,作短期合作研究。

科研奖励:

获全国科学大会奖(1978年)

国防科委多次嘉奖,江苏省科学大会奖(1978年)

国家自然科学三等奖(1991年)

国家教委科技进步一等奖和二等奖(1990和1996)

教育部提名国家科学技术奖自然科学奖一等奖(2004)

多次受邀在学术会议上做大会报告,分会邀请报告

发明专利:

1. Y2O3 纳米带负载 Ag 催化剂及其合成方法和应用

2. 纳米级氧化银及其生产工艺

3. 一种纳米级金粉及其制备方法

4. 铁磁性碳纳米管的合成方法

5. 耐高温烧结金水及其生产方法

6. 一种包含金属纳米线碳纳米管的合成方法

论文专著:

1. M. Han, Z. Xu,* et al., “Controllable synthesis and magnetic properties of cubic and hexagonal phase nickel nanocrystals”, Adv. Mater., 2007, 19, 1096-1100.

2. F. F. Tao, Z. Xu,* et al., “An easy way to construct an ordered array of nickel nanotubes: The triblock-copolymer-assisted hard-template method”, Adv. Mater., 2006, 18 (16), 2161.

3. Q. Liu, Z. Xu,* et al., “Nanometer-sized nickel hollow spheres”, Adv. Mater., 2005, 17(16), 1995.

4. J. C. Bao, Z. Xu,* et al., “Facial synthesis of hollow nickle submicrometer spheres”, Adv. Mater., 2003, 15(21), 1832-1835.

5. J. C. Bao, Z. Xu,* et al., “A facile method for creating an array of metal-filled carbon nanotubes”, Adv. Mater., 2002, 14(20), 1483-1486.

6. J. C. Bao, Z. Xu,* et al., “An array of concentric composite nanostructures of zirconia nanotubules/cobalt nanawires, preparation and magnetic properties”, Adv. Mater., 2002, 14(1), 44-47.

7. J. C. Bao, Z. Xu,* et al., “Template synthesis of an array of nickel nanotubles and Its magnetic behavior”, Adv. Mater., 2001, 13(21), 1631-1633.

8. H. Q. Cao, Z. Xu,* et al., “Template synthesis of an array of cobalt nanowires encapsulated with polyaniline nanotubules and its magnetic behavior”, Adv. Mater., 2001, 13(2), 121-123.

9. H. Q. Cao, Z. Xu,* et al., “Sol-gel template synthesis of array of single crystal CdS nanowires in porous alumina template”, Adv. Mater., 2001, 13(18), 1393-1394.

10. F. F. Tao, Z. Xu,* et al., “Concentric sub-micrometer-sized cables composed of Ni nanowires and sub-micrometer-sized fullerene tubes”, Adv. Func. Mater., 2007, 17, 1124.

11. N. Shi, Z. Xu,* et al., “A smart supramolecular hydrogel exhibiting pH-modulated viscoelastic properties”, Adv. Func. Mater., 2007, 17, 1837.

12. M. Han, Z. Xu,* et al., “Large-scale synthesis of single-crystalline RE2O3 (RE= Y, Dy, Ho, Er) nanobelts by a solid-liquid-phase chemical route”, Chem. Eur. J., 2008, 4, 1615.

13. N. Shi, Z. Xu,* et al., “Self-assembly of two different hierarchical nanostructures on either side of an organic supramolecular film in one step”, Chem. Eur. J., 2008, 14(20), 6255-6259.

14. Y. Jiang, Z. Xu,* et al., “Fabrication of monodisperse colloidal array with confinement effects”, Chem. Commun., 2006, 75-77.

15. J. C. Bao, Z. Xu,* et al., “A novel nanostructure of nickel nanotubes encapsulated in carbon nanotubes”, Chem. Commun., 2003, 208-209.

16. H. Q. Cao, Z. Xu,* et al., “Sol-gel synthesis of array of C70 nanowires in porous alumina template”, Chem. Commun., 2001, 541-542.

17. A. H. Yuan, Z. Xu,* et al., “An unusual three-dimensional porous framework complex {[Cu(en)2[KCr(CN)6]]}∞ from a temperate self-assembly reaction”, Chem. Commun., 2000, 1297-1298.

18. Z. Z. Wu, Z. Xu,* et al., “A new bonding mode of oximato ligand to a metal:synthesis and X-ray crystal structure of bis[acctone oximato bis(cyclopentadienyl) gadolinium] [(C5H5)2Gd(μ-2)-ONeMe2]]2” J. C. S. Chem. Commun., 1994, 813.

19. Z. Wu, Z. Xu,* et al., “Dehydrogenation reaction of organolanthanide alkoxides and X-ray crystal structure of reaction product [(C5H5)2Yb(μ-OCH=C=CH2)]2”, J. C. S. Chem. Commun., 1993, 1494.

20. X. Li, Z. Xu,* et al., “Two growth modes of metal oxide in the colloidal crystal template leading to theformation of two different macroporous materials”, Chem. Mater., 2007, 19, 5424.

21. J. C. Bao, Z. Xu,* et al., “An array of concentric composite nanostructure of metal nanowires encapsulated in Zirconia nanotubes: prepartion, characterization and magnetic properties”, Chem. Mater., 2002, 14(11), 4709-4713.

22. X. P. Shen, Z. Y. Jiang, Z. Xu,* et al., “One-step construction of ZnS/C and CdS/C one-dimensional core–shell nanostructures”, J. Mater. Chem., 2007, 17, 1326-1330.

23. Q. F. Zhou, Z. Xu,* et al., “Shape-controlled synthesis of nanostructrured gold by a protection-reduction technique”, J. Mater. Chem., 2002, 12, 384-387.

24. H. Q. Cao, Z. Xu,* et al., “Iron nanowires encapsulated in polyaniline nanotubules and its magnetic behavior”, J. Mater. Chem., 2001, 11(3), 958-960.

25. H. Li, Z. Xu,* et al., “Template-free fabrication of fullerene (C60, C70) nanometer-sized hollow spheres under solvothermal conditions”, Carbon, 2008, 46(13), 1736-1740.

26. M. Han, Z. Xu,* et al., “Hollow nickel microspheres covered with oriented carbon nanotubes and its magnetic property”, Carbon, 2006, 44 (2), 211-215.

27. X. Li, Z. Xu,* et al., “Controllable fabrication, growth mechanisms, and photocatalytic properties of hematite hollow spindles”, J. Phys. Chem. C. 2009, 19, 2837-2845.

28. M. Han, Z. Xu,* et al., “Synthesis, characterization, and physicochemical properties of well-coupled Y2O3 nanobelt-Ag nanocrystals nanocomposites,” J. Phys. Chem. C. 2008, 112(46), 17893-17898.

29. C. Gao, Z. Xu,* et al., “Hierarchical construction of composite hollow structures of Co@CoO and their magnetic behavior”, J. Phys. Chem. C. 2008, 112(25), 9272-9277.

30. C. Gao, Z. Xu,* et al., “Controllable fabrication of mesoporous MgO with various morphologies and their absorption performance for toxic pollutants in water,” Crystal Growth & Design, 2008, 8(10), 3785-3790.

31. M. Guan, Z. Xu,* et al., “A host crystal for the Rare-earth ion dopants: synthesis of pure and Ln-doped urchinlike BiPO4 structure and its photoluminescence”, Crystal Growth & Design, 2008, 8(8), 2694-2697.

32. F. Tao, Z. Xu,* et al., “Fabrication of nickel hydroxide microtubes with micro- and nano-scale composite structure and improving electrochemical performance”, Crystal Growth & Design, 2008, 8(7), 2157-2162.

33. J. Sun, Z. Xu,* et al., “Selective synthesis of gold cuboid and decahedral nanoparticles regulated and controlled by Cu2+ ions”, Crystal Growth & Design, 2008, 8(3), 906-910.

34. Y. Ni, Z. Xu,* et al., “Shape-controllable preparation of PbS crystals by a simple aqueous-phase route”, Crystal Growth & Design, 2004, 4, 759

35. M. Guan, Z. Xu,* et al., “Facile preparation method for rare earth phosphate hollow spheres and their photo-luminescence properties”, Langmuir, 2008, 24(15), 8280-8283.

36. J. C. Bao, Z. Xu,* et al., “Synthesis and magnetic behavior of array of nickel-filled carbon nanotubes”, Appl. Phys. Lett., 2002, 81(24), 4592-4594.

37. H. Q. Cao, Z. Xu,* et al., “Array of polyaniline nanotubules filled with nickel nanowires and its magnetic behavior”, Appl. Phys. Lett., 2001, 78(11), 1592-1594.

38. M. Y. Guan, Z. Xu,* et al., “A novel cobalt submicro-wire network and its magnetic properties”, Chemphyschem, 2007, 8, 2182.

39. W. L. Zhang, Z. Xu,* et al., “Controllable synthesis of CoO nanosheets and their magnetic properties”, Chemphyschem, 2007, 8, 2091.

40. M. Y. Guan, Z. Xu,* et al., “Synthesis and luminescence of CePO4 and CePO4: Tb hollow and core-shell microspheres composed of single-crystal nanorods”, Nanotechnology, 2007, 18, 415602.

41. H. J. Liu , Z. Xu,* et al., “A facile template-free route for synthesis of hollow hexagonal ZnS nano- and submicro-spheres”, Nanotechnology, 2005, 16 (12), 2908-2912.

42. X. P. Shen, Z. Xu,* et al., “Fabrication, characterization and field emission properties of large-scale uniform ZnO nanotube arrays”, Nanotechnology, 2005, 16(10), 2039-2043.

43. Z. Y. Suo, X. W. Wei, Z. Xu,* “New charge transfer complexes from dicyanodihydrofullerene and metallocene”, J. C. S. Dalton Trans., 1998, 22, 3875.

44. N. Shi, Z. Xu,* et al., “Uncommon hexagonal microtubule based gel from a simple trimesic amide”, New J. Chem., 2008, 32(11), 2011-2015.

45. X. P. Shen, Z. Xu,* et al., “Crystal structure and magnetic behavior of a three-dimentional cyano-bridged assembly [CuL1]2[Cr(CN)6]ClO4•0.5H2O (L1=3, 10-dcpropyl-1, 3, 5, 8, 10, 12-hexaazacyclo-tetradecane)”, New J. Chem., 2004, 28 (8), 996-999.

46. M. Li, Z. Xu,* X. Z. You, X. Y. Huang, “One step synthesis and some reactions of ethyl 2, 3-dimethyl-8-(Ethyl-2', 3'-dimethyl-4'-Carboxylate) pyrrolo [2, 1-a] isoquinoline-1-carboxylate”, J. C. S. Perkin Trans. I, 1994, 2787.

47. X. W. Wei, Z. Y. Suo, Z. Xu,* “New chemical method for selective generation of C70n-(n=1, 2, 3) anion and formation and properties of an aqueous colloidal solution of C70”, J. C. S. Perkin. Trans. II, 1999, (1), 121-126.

48. X. W. Wei, M. F. Wu, Z. Xu,* et al., “Selective solution-phase generation and oxidation reaction of C60n-(n=1, 2) and formation of an aqueous colloidal solution of C60 ”, J. C. S. Perkin Trans. II, 1997, 1389.

49. Y. Wu, X. P. Shen, Z. Xu,* et al., “New double-1, 2-amide-bridged calix[4]arene by aminolysis of the calix[4]arene esters”, Tetrahedron Lett., 1999, 40, 5749-5752.

50. M. F. Wu, X. W. Wei, L. Qi, Z. Xu,* “A new method for facile and selective generation of C60- and C602- in aqueous caustic/THF (or DMSO)” Tetrahedron Letters, 1996, 37(41), 7409.

51. X. P. Shen, Z. Xu,* et al., “Single crystal structure and magnetic behavior of a molecule-based ferrimagnet Mn[Mn0.2Cr0.8(CN)6]4H2O”, Eur. J. Inorg. Chem., 2007, 12, 1698-1702.

52. J. C. Bao, Z. Xu,*, et al., “Fabrication of cobalt nanostructures with different shapes in Alumina template”, Scripta Materialia, 2004, 50(1), 19-23.

53. X. Li, Z. Xu,* et al., “3-D ordered macroporous cuprous oxide: fabrication, optical, and photoelectrochemical properties”, J. Coll. Inter. Sci., 2007, 308, 460.

54. G. Yin, D. Xu, Z. Xu,* “Spectral behavior of cis-2’, 5’-dipyridinylpyrrolidino [3’, 4’: 1, 2][60] fullerene and its coordination complex with zinc porphyrin (ZnTPP)”, Chem. Phys. Lett., 2002, 365, 232-236.

55. H. B. Liu, Z. Xu,* et al., “Photo-physical properties of the transition metal ions complexes of the calix[4]arene derivatives”, Chem. Phys. Lett., 2001, 350, 441-446.

56. H. B. Liu, Y. Xu, B. Li, G. Yin, Z. Xu,* “A new highly selective calix[4]arene-based fluorescent probe for Ca2+”, Chem. Phys. Lett., 2001, 345(5-6), 395.

57. Z. Y. Suo, Z. Xu,* et al., “Optical limiting performance of dicyanodihydrofullerene”, Chem. Phys. Lett., 2001, 342, 497-502.

58. Z. Suo, Y. Zhang, J. Zhang, Z. Xu,* C. Li, Z. Bai, “Generation and characterization of C60(CN)2n-(n=1, 2, 3)”, Chem. Phys. Lett., 1999, 315, 321-326.

59. X. Wei, Z. Suo, Z. Xu,* “New solution-phase method for the preparation of alkali-earth metal fulleride Ca(C60)2, Ba(C60)2: synthesis and characterization with ESR, UV-NIR, IR and Raman spectroscopy”, Chem. Phys. Lett., 1999, 310, 15-20.

60. X. W. Wei, C. Hu, Z. Y. Suo, P. Wang, W. Zhang, Z. Xu,* “Solid state 13C NMR and optical nonlinearities study of C60 trimethylenediamine adducts”, Chem. Phys. Lett., 1999, 300, 385-391.

61. M. Li, Z. Xu,* et al., “Photophysical properties of dodecaphenyl-porphyrins with different substitutes”, Chem Phys. Lett., 1998, 288, 459.

62. X. W. Wei, Z. Xu,* “Alkali-metal fullerides MC60(THF)x (M=Li, Na, K): a new solution phase method for the preparation and characterization with EPR, UV-NIR and IR spectroscopy”, J. Organometal. Chem., 2000, 599(1), 69-73.

63. Z. Z. Wu, Z. N. Huang, Z. Xu,* et al., “Synthesis and thermol stability of binuclearbiscyclopentadienyl lanthanide thiolates, X-ray crystal structure of [CP2Yb(μ-S CH2CH2CH3)2 ”, J. Organomet. Chem., 1996, 506, 25.

64. X. G. Zhou, H. Z. Ma, Z. Z. Wu, X. Z. You, Z. Xu,* “Synthesis and structure of a new organolanthanide oxide complex, (CH3C5H4Yb4(μ-Cl)6(μ3-Cl)(μ4-O)(THF)3”, J. Organomet. Chem., 1995, 503, 11.

65. Z. Z. Wu, Z. Xu,* X. Y. Huang, “Dehydrogenation of organolanthanide alkoxides and X-ray crystal structures of reaction product [(C5H5)Ln(μ-OMeC=CHCH3)]2, (Ln = Dy, Yb)”, J. Organomet. Chem., 1994, 483, 107.

66. Z.-Z. Wu, Z. Xu,* et al., “Synnthesis and X-ray crystal structure of the cyclopentadienyl nitrito complex of ytterbium (C5H5)2Yb(NO2)THF”, J. Organomet. Chem., 1993, 455(1-2), 93.

67. Q. Liu, Z. Xu,* et al., “Three-dimensional five-connected coordination polymer [M2(C3H2O4)2(H2O)2(μ2-hmt)]n with 4466 topologies”, J. Solid State Chem., 2004, 177, 4701-4705.

68. N. Shi, Z. Xu,* et al., “Anions bonded on the supramolecular hydrogel surface as the growth center of biominerals”, Colloids and Surfaces, B: Biointerfaces, 2008, 66(1), 84-89.

69. Q. Liu, Z. Xu* et al., “Three-dimensional five-connected coordination polymer [M2(C3H2O4)2(H2O)2(mu2-hmt)]n with 4466 topologies (M = Zn, Cu; hmt = hexamethylenetetramine)”, J. Solid. State. Chem., 2004, 177 (12), 4701-4705. 1.486

70. C. Gao, Z. Xu,* et al., “Ordered arrays of magnetic metal nanotubes and nanowires encapsulated with carbon tubes”, J. Nanosci. Nanotechno., 2008, 8(9), 4494-4499.

71. Q. Liu, Z. Xu,* et al., “Large-scale synthesis of single crystal silver nanowires by a sodium diphenylamine sulfonate reduction process”, J. Nanosci. Nanotechno., 2006, 6 (1), 231-234.

72. J. He, Z. Xu,* et al., “Crystal hierarchically splitting in growth of BaWO4 in positive cat-anionic microemulsion”, J. Cryst. Growth, 2008, 310(21), 4581-4586.

73. X. P. Shen, Z. Xu,* et al., “Construction and photoluminescence of In2O3 nanotube array by CVD-template method”, J. Cryst. Growth, 2005, 276(3-4), 471-477.

74. Y. H. Ni, Z. Xu,* et al., “A novel aqueous-phase route to prepare flower-shaped PbS Micro crystals”, J. Cryst. Growth, 2004, 262, 399-402.

75. X. P. Shen, Z. Xu,* et al., “Template-based CVD synthesis of ZnS nanotube arrays”, Chemical Vapor Deposition, 2005, 11 (5), 250-253.

76. Q. Liu, Z. Xu,* et al., “Solution phase synthesis of CuO nanorods”, Mater. Chem. and Phys., 2006, 98 (2-3) 519-522.

77. Q. Liu, Z. Xu,* et al., “High yield synthesis of PbS nanocubes using one-step solid-state reaction in the presence of an anionic surfactant”, Mater. Chem. and Phys., 2005, 89(2-3), 379-382.

78. X. P. Shen, Z. Xu,* et al., “Synthesis, characterization and magnetic properties of Co3O4 nanotubes”, Appl. Phys. A-Mater. Sci. & Proc. 2008, 91, 47.

79. Y. H. Ni, Z. Xu,* et al., “Self-assembly of CuS nanoparticles to solid, hollow, spherical, tubular structures in a simple aqueous-phase reaction”, Appl. Phys. A-Mater. Sci. & Proc. 2004, 79(8), 2007-2011.

80. Y. H. Ni, Z. Xu,* et al., “Fabrication and characterization of hollow cuprous sulfide (Cu2-xS) microspheres by a simple template-free route”, Inorg. Chem. Comm., 2003, 6, 1406-1408.

81. B. L. Li, Z. Xu,* et al., “Synthesis and structure of novel coordination polymer: polycatenated {[Mn(bipy)(azpy)2(NCS)2]•H2O}n”, Inorg. Chem. Comm., 2001, 4, 451-453.

82. J. Z. Zou, Z. Xu,* et al., “Synthesis, Structure and magnetic properties of a new polymeric compounds containing manganese(II)-Pzdc (Pzdc: 2,3-pyrazinedicarboxylic acid)”, Polyhedron, 1999, 18, 1597-1512.

83. J. Z. Zou, Q. Liu, Z. Xu,* et al, “A novel three dimension network Copper(II) comples {[(Cudien)2(Cudien•H2O)TCB](ClO4)2•H2O}n”, Polyhedron, 1998, 17(11-12),1863.

84. M. X. Li, Z. Xu,* et al., “A novel hydroxo-bridged ferric bisubstituted keggin heteropolytungstate dimer: synthesis and crystal structure of (Me4N)10[Fe4(OH)4(PW10O37)2]H2O”, Polyhedron, 1998, 17(21), 3721.

85. H. Xu, J.-Z. Zou, J.-Y. Li, Z. Xu*, X.-Z. You, G.-C. Guo, J.-S. Huang, “Crystal structure and magnetic properties of a new oxo-centred basic benzoic bridging mixed-valence trinuclear complex MnⅢCoⅢMnⅡO(PhCOO)6Py3”, Polyhedron, 1997, 16(8), 1377.

86. H. Xu, J. Li, J. Zou, Z. Xu,* X. You, G. Guo, J. Huang, H. Zhuang, “Crystal structure and magnetic properties of a new oxo-centred basic benzoate bridging heterotrinuclear compound[Cr2MnO(PhCOO)6Py3][CrO3Cl]”, Polyhedron, 1997, 16(8), 1371.

87. Z. Z. Wu, Z. N. Huang, Z. Xu,* et al., “Synthesis and structure of binuclear bis-cyclopentadienyl ytterbium n-propyl. thiolate [C5H5]2Yb- SCH2CH2CH3(CH3)2]”, Polyhedron, 1996, 15(19), 3427.

88. J. Y. Li, H. Xu, Z. Xu,* et al., “Synthesis,molecular structure and magnetic properties of [Mn11CrO12(CH3CO2)16(H2O)4]4H2O with A s=8 Ground State”, Polyhydron, 1996, 15(19), 3325-3329.

89. H. Xu, J. Li, J. Zou, Z. Xu,* “Crystal structure and magnetic properties of a new heterotrinuclear compound”, Polyhedron, 1996, 15(19), 3325.

90. M. X. Li, Z. Xu,* et al., “Crystal structure and magnetic properties of [Mn4](OOCCH2CH2COO)2(2, 2'-bipy)8](ClO4)4•3H2O”, Polyhedron, 1996, 15(3), 535.

91. Z. Z. Wu, Z. N. Huang, Z. Xu,* et al., “Synthesis and characterization of dinuclear organclanthanide alkoxides, X-ray crystal structure of [C5H5]2Yb(μ-O(CH2)4CH3)2 and [C5H5]2Yb(μ-OCH2 CH2CH3(CH3)2)”, Polyhedron, 1996, 15(1), 13.

92. J. Li, J. Zou, M. Wu, Z. Xu,* et al., “Synthesis, crystal structure and magnetic properties of a oxo-bridged binuclear iron (III) compound [Fe(phen)2phCOO]]2OCl2•7H2O”, Polyhedron, 1995, 14, 3519.

93. Z. Z. Wu, Z. Xu*, X. Z. You, et al., “Formation and crystal structures of (C5H5)3Sm•OC4H8 and (C5H5)3Dy•OC4H8”, Polyhedron, 1994, 13(3), 379.

94. M. Li, Z. Xu,* X. Z. You, X.Y. Huang, “X-ray crystal structure, spectral and magnetic properties of a mixed ligand dinuclear complex [Cu(phen)(Sa)(ClO4)]2”, Polyhedron, 1994, 14(5), 639.

95. X. G. Zhou, Z. Xu,* et al., “Synthesis and structure of monocydo-pentadienyl yttrium(Ⅲ) dichloride tris(tetrahydrofuranate)”, Polyhedron, 1994, 13(3), 375.

96. H. Xu, J. Li, Z. Wu, J. Zou, Z. Xu,* et al., “Synthesis and X-ray crystal structure of mixed valent cobalt complex Co2Cl5(Py)5”, Polyhedron, 1993, 12(18), 2261.

97. M. Li, Z. Xu* et al., “Crystal structure and mass spectra of a copper(I) complex with a chain arrangement: [μ-4, 4'-bipy-Cu(TTA)]2”, Polyhedron, 1993, 12(8), 921.

98. Z.-Z. Wu, Z. Xu* et al., “Synthesis and crystal structure of monocyclo-pentadienyl holmium dichloride tris (tetrahydrofuran)”, Polyhedron, 1993, 12(7), 795.

99. Z.-Z. Wu, Z. Xu* et al., “Crystal structure and magnetic property of dicyclopentadienylholmium chloride [(C5H5)2HoCl]2”, Polyhedron, 1993, 12(6), 677.

100. Z. Wu, Z. Xu*, X. You, et al., “Synthesis and characterization of binuclear organolanthanide complexes involving cyclopentadienyl and n-propyloxide ligands. X-crystal structure of [(C5H5)2Yb(μ-OCH2CH2CH3)]2”, Polyhedron, 1992, 11, 2673.

101. S. Gou, X. You, Z. Xu,* et al., “Study on the transition metal complexes of tridentate schiff base ligand containing S, N, and O atoms: synthesis, structure and properties of mononuclear metal complexes”, Polyhedron, 1991, 10, 488.

102. S. Gou, X. You, Z. Xu,* et al., “Transition metal complexes of the Schiff bases derived from S-alkyldithiocarbazate with 2-pyridinecarboxaldehyde N-oxide III. Synthesis, properties and structure of nickel(II) complexes”, Polyhedron, 1991, 10, 2659.

103. Z. Xu,* E. C. Alyea, et al., “Stuctural characterization of a thiosemicarbazone derived from 2-acetyl pyridine N-oxide and its dimeric copper(II) nitrate complex”, Polyhedron, 1991, 10, 1625.

104. S. Gou, P. Zheng, Z. Xu,* et al., “Transition metal complexes of the Schiff bases drived from S-alkydithiocarbazate with 2-pyridine carbox-aldehyde N-oxide II. Synthesis, properties and structure of five coordinate copper(II) complexes”, Polyhedron, 1991, 10(12), 1363.

105. S. Gou, Z. You, Z. Xu,* et al., “Preparation and crystal structure of deprotonated S-methyl-N-(prydine N-oxide-2- ylmethylidene) dithiocarbazate pyridine nickel(II) perchlorate [Ni(C8H8 N3OS2) (C5H5N) ]ClO4”, Polyhedron, 1991, 10(1), 37.

106. E. C. Alyea, Z. Xu,* et al., “The structure of a copper(I)-schiff base complex[Cu N(CH2CH2N=CHC6H5)3Bph4”, Polyhedron, 1990, 9(5), 739.

107. S. Gou, X. You, Z. Xu,* et al., “Transition metal complex of the Schiff base derived from S-alkyldithiocarbazate with 2-pyridine carboxaldehyde N-oxide I. synthesis, properties and structure of four coordinate copper(II)”, Polyhedron, 1990, 9, 2981.

108. E. C. Alyea, Z. Xu,* “Some copper(I) and copper(II) complexes of two new potentially heptadentate tripodal Schiff base ligands”, Polyhedron, 1990, 9, 2463.

109. M. Li, Z. Xu,* et al., “The coordination dimer from ZnTPP and M(m-PyOMP) (M = H2 or Cu): spectroscopic properties and crystal structure”, Inorg. Chim. Acta, 1997, 261, 211.

110. M. Gu, T. B. Tang, Y. Wu, Z. Xu,* et al., “Order-disorder transition in P-tert-butylcalix[8]arene - C60 Complex(1:1)”, Phys. Lett. A., 1999, 263, 131-135.

111. Y. H. Ni, Z. Xu,* et al., “Microwave-assisted template synthesis of an array CdS nanotubes”, Mater. Letter, 2004, 58(22-23), 2754-2756.

112. Q. F. Zhou, Q. Wang, Z. Xu,* et al., “The preparation of potassium silver cyanide by air blast cyanidation of superfine silver powder”, Mater. Lett., 2003, 57(13-14), 1915-1918.

113. H. J. Liu, Z. Xu*, et al., “Fablication of submicrom Cu2O hollow spheres in an O/W/O multiemulsion”, Colloids and Surfaces A: Physicochem. Eng. Aspects, 2004, 235, 79-82.

114. X. P. Shen, Z. Xu,* et al., “Synthesis and aracterization of Bi2S3 faceted nanotube bundles”, Solid State Communications, 2006, 140(3-4), 116-119.

115. X. P. Shen, Z. Xu,* et al., “Fabrication of well-aligned CdS nanotubes by CVD-template method”, Solid State Communications, 2005, 133(1), 19-22.

116. A. D. Xia, Z. Xu,* et al., “Characteristics of heterojunction diode of C60/chloroindium phthalocyanine”, Solid State Communications, 1995, 95(10), 713.

117. M. Li, J. Zou, Z. Xu,* X. You, “7, 8, 17, 18-Tetrabromo-5, 10, 15, 20- tetra phenylporphyrin and It’s metal derivatives photophysical properties and electronic structure”, Spectrochim. Acta Part A, 1997, 53, 2109.

118. Q. Liu, Z. Xu,* et al., “Synthesis and sructure of a novel three-dimensional coordination polymer[Cd3(μ3-hmt)2(μ2-C4H2O4)2(H2O)6]SO4.4H2O with (3,4) Connected Topological motifs (hmt=hexamethylenetetramine)”, J. Mol. Struct. 2005, 733(1-3), 25-28.

119. X. P. Shen, Z. Xu,* et al., “The first cyano-bridged heptanuclear Mn(Ⅲ)6Fe(Ⅲ)cluster: crystal structucture and magnetic properties”, J. Mol. Struct., 2003, 657(1-3), 325-331.

120. B. L. Li, Z. Xu,* et al., “Synthesis and crystal structure of two cobalt complexes: [Co2(4,4/-azpy)5(H2O)6][ClO4]4.(H2O)10.(4,4/-azpy)4 with a novel two-dimensional large rectangle organic-inorganic hybrid network and one-dimensional chain complex {[Co(3,3/-azpy)(H2O)4][ClO4]2. [3,3/-azpy]3}n”, J. Mol. Struct., 2001, 597(No.1-3), 21-30.

121. Q. Liu, Z. Xu,* et al., “Large-scale synthesis of single-crystalline CuO nanoplatelets by a hydrothermal process”, Mater. Res. Bull., 2006, 41 (4), 697-702.

122. Y. H. Ni, Z. Xu,* et al., “Rapid fabrication and optical properties of zinc sulfide nanocrystallings in a heterogeneous system”, Mater. Res. Bull., 2004, 39(12), 1967-1972.

123. N. Shi, Z. Xu,* et al., “Coordination driving self-assembly of gold nanoparticles and tetrapyridylporphine into hollow spheres”, Chem. Lett., 2005, 34(11), 1468-1469.

124. X. P. Shen, Z. Xu,* et al., “An efficient template pathway to synthesis of ordered metal oxide nanotube arrays using metal acetylatetonates as single-source molecular precursors”, Chem. Lett., 2004, 33(9), 1128-1129.

125. B. L. Li, Z. Xu,* et al., “The first mixed-valence CoII III intrilotriacetate and 4, 4’-azobispyridine two ligand compex: synthesis and structure characterization of[CoIICoIII(NTA)2(azpy)2(H2O)]n∙n[CoII2CoIII(NTA)2(azpy)4(H2O)6∙4nH2O] with a new open sidearm ladders structure”, Chem. Letter, 2001, 214.

126. B. L. Li, Z. Xu,* et al., “Self-assembly of a novel infinite triple helices coordination polymer: polycatenated {[Co(bipy)(azpy)2(NCS)2].H2O}n via hydrogen-bonding interaction”, Chem. Lett., 2001, 9, 902-903.

127. Y. Xu, B. L. Li, Z. Xu,* et al., “Liquid crystalline thiadiazole derivatives: new ferroeletric thiadiazole derivatives”, Liquid Crystals, 2002, 29(2), 199-202.

128. P. Wang, Z. Xu*, et al., “Substituents effect on the nonlinear optical properties of C60 derivatives”, Optics Commun., 2001, 192, 387-391.

129. H. Zhou, S. G. Yang, Z. Y. Suo, Z. Xu,* et al., “Preparation and magnetic properties of array of Ni nanowire”, Acta Phys. Sinica, 1999, 48 (12), 8111.

130. H. B. Liu, B. L. Li, Z. Xu,* et al., “Two novel self-assemblies of the calyx[4]arene Derivertives and their structures”, J. Inclusion phenomena and macrocyclic chemistry, 2003, 45, 9-11.

131. Q. Liu, Z. Xu,* et al., “Solvothermal synthesis of CoFe2O4 hollow spheres”, J. Mater. Sci. 2007, 42, 10113.

132. Q. Liu, Z. Xu,* et al., “Synthesis of nearly monodispersive gold nanoparticles by a sodium diphenylamine sulfonate reduction process”, J. Mater. Sci., 2006, 41(12), 3657-3662.

133. Q. F. Zhou, Z. Xu,* et al., “Preparation of nano-scale plate silver powders by visible light induced method”, J. Mater. Sci., 2004, 39, 2487.

134. Q. Liu, B. L. Li, Z. Xu,* et al., “Synthesis, crystal structure and magnetic property of [Mn2(mal)2(H2O)2(μ2-hmt)]n: a novel three-dimensional network self-assembled by HMT”, J. Coord. Chem., 2003, 56(9), 771-777.

135. Q. Liu, Z. Xu,* et al., “A New azide-bridged three-dimensional supermolecular magnanese(II) compound: synthesis, crystal structure and magnetic properties”, J. Coord. Chem., 2002, 55(9), 1021-1027.

136. B. L. Li, Z. Xu,* et al., “Synthesis, structure and characterization of the cyano-bridged heteropolymer [Cu(tn2)2[Co(cn)6(ClO4)•2H2O] with a two-dimensional framework”, J. Coord. Chem., 2002, 55(10), 1191-1198.

137. B. L. Li, Z. Xu,* et al., “Synthesis, characterization and crystal structure of a one-dimensional chain [Cu(2,2’-bipyridine)(4,4’azobispyridine)(H2O)][ClO4] with rhomibic channels”, J. Coord. Chem., 2002, 55(10), 1183-1189.

138. J. Z. Zou, M. Li, Z. Xu,* et al., “A cyano bridging copper(I)-iron(III) binuclear complex (cutren)Fe(CN)5NO2•2H2O: crystal structure and magnetic properties”, J. Coord. Chem., 1998, 43, 273.

139. J. Zou, Z. Xu,* X. Huang, W.-L. Zhang, X.-P. Shen, Y.-P. Yu, “Crystal structure and magnetic properties of heterotrinuclear complex, (Cutren)2Fe(CN)6•12H2O”, J. Coord. Chem., 1997, 42, 55.

140. H. Xu, J. Zou, J. Li, Z. Xu,* X. You, G. Guo, J. Huang, “A new oxo-centred, mixed-alence heterotrinuclear complex, Mn(Ⅲ)Ni(Ⅲ)Mn(Ⅱ)O(PhCOO)6Py3 crystal structure and magnetic properties”, J. Coord. Chem., 1997, 42, 45.

141. Z. Wu, Z. Xu*, X. You, et al., “Crystal structure of (cyclopentadienyl)- dichlorogadolinium(Ⅱ)-tri(Tetrahydrofuran)”, J. Coord. Chem., 1992, 26, 329.

142. L. Qi, C. Chang, X. W. Wei, Z. Xu,* et al., “Electrospray ionization mass spectroscopy analysis of the netral fullerenes”, Acta. Chem. Sinica, 1997, 55, 498.

143. M. Li, Z. Xu,* et al., “Syntheses and magnetic properties of Cu(II), Ni(II) complexes bridged by 4, 4'-bipyridine, pyrazine and imidazole”, Acta. Chim. Sinica., 1995, 53, 847.

144. J. Z. Zou, Z. Xu,* et al., “Electronic structure of H2TPPBr4 and MTPPBr4 and crystal structure of Ni(TPPBr4))”, Acta Chim. Sinica, 1994, 52, 683.

145. M. X. Li, Z. Xu*, “Synthesis, structure and magnetic properties of [M(TTA)2•μ-4, 4'-bipy]n”, Acta Chim. Sinica, 1994, 52, 174.

146. S. H. Gou, Z. Xu,* et al., “Study on the tripodal transition metal complexes with ferrocenyl groups as arms”, Acta Chim. Sinica, 1992, 50, 1105.

147. Z. Xu,* J. H. Lin, et al., “Synthesis and molecular structure of Co[(C2H5O)2PS2]2•2Py”, Acta Chim. Sinica, 1989, 47, 623.

148. Z. Xu,* et al., “The study on thermodynamic properties of adduct formation between bis-(O, O'-dioctyldithiophosphato) nickel(II) and the primary alkanol by GLC method”, Acta Chim. Sinica, 1988, 46, 740.

149. S. Han, Z. Xu,* et al., “Electron paramagnetic resonance study on Cu[(C6H11O)2PS2]2 complex single crystal”, Acta Chim. Sinica, 1988, 46, 302.

150. Z. Xu,* X. You, et al., “The crystal structure of binuclear copper (II) complex [Cu2](C20H12ClN2O3)OCH3H2O of the bis-schiff base”, Acta Chim. Sinica, 1985, 43, 1039.

151. X. P. Shen, Z. Xu,* et al., “Synthesis, crystal structures and magnetic properties of two cyano-bridged two-dimensional assemblies[Fe(salpn)]2[Fe(CN)5NO] and [Fe(sapn)2][Ni(CN)4]”, Tran. Met. Chem., 2004, 29, 100-106.

152. Q. Liu, B. L. Li, Z.Xu,* “A novel three-dimensional coordination polymer [Cd2(C3H2O4)2(H2O)2(μ2-hmt)]n : synthesis and crystal structure”, Tran. Met. Chem., 2002, 27, 786-789.

153. X. P. Shen, Z. Xu,* et al., “Crystal structure of a cyanide-bridged heptanuclear manganese(III)-chromium(III) complex with a ground state s=21/2”, Trans. Met. Chem., 2002, 27, 372-376.

154. Q. Liu, B. L. Li, Z. Xu,* et al., “Synthesis and crystal structure of [Ag2(-hmt)(NO2)]n. A two-dimensional network with square cavties self-assembled by hmt”, Tran. Met. Chem., 2001, 26, 369-371.

155. B. Li, Z. Xu*, Z. Cao, L. Zhu, K. Yu, “One dimensional chain copper complexes [Cu(dien)(btrz)(ClO4)2] and [Cu(en)2(btrz)(ClO4)2]”, Trans. Met. Chem., 1999, 24, 622-627.

156. J. Z. Zou, Z. Xu,* et al., “Synthesis and magnetic properties of one dimensional linear chain structure cyano bridging complex(Cuteta•2H2O) [CutetaFe(CN)6]ClO4•H2O”, Trans. Met. Chem., 1998, 23, 477.

157. J. Z. Zou, Z. Xu,* et al., “Crystal structure and magnetic properties of a new polymer (Cu)pzdcH)2•2H2O]n”, Trans. Met. Chem., 1998, 23(4), 481.

158. J. Z. Zou, Z. Xu,* “Crystal structure and strong antiferromagnetic interaction of a terephalatebridged binuclear Copper(II) complex (Cudipn)2 (μ-TPHA)(ClO4)2(dipn:N(3-aminopropyl)-1,3-propanediamine)”, Trans. Met. Chem., 1998, 23(3), 305.

159. Z. Wu, Z. Xu,* et al., “Synthesis and study on thermal stability of cyclopentadienyl (or Indenyl) early lanthanide complexes involving 8-quinolinolato and O-aminophenolato chelate ligands” Synth. React. Inorg. Met.-Org. Chem., 1993, 23(7), 1155.

160. J. H. Lin, Z. Xu,* et al., “EPR study on single crystal of Bis-[O,O'-(2,2'-bisphenyl)dithiophosphato] copper(II) complex”, Chin. Sci. Bull., 1989, 6, 558.

161. X. Zhou, Z. Wu, Z. Xu,* et al., “Thermodytic reactivity of Cp2HoCl and X-ray structure of the thermolysis product [(C5H3CH=CHCH2C=CHC5H4)2Ho2Cl2”, Chin. Sci. Bull., 1995, 40(7), 552.

162. X. Z. You, Z. Xu,* et al., “Equilibrium constant of adductive reaction between Bis-(O,O'-Dicyclohexyldithiophosphato) Nickel(II) and benzylamine and crystal structure of adducts Ni[(C6H11O)2PS2]2•2NH2CH2C6H5”, Chin. Sci. Bull., 1992, 37(8), 657.

163. Y. H. Ni, Z. Xu,* et al., “PbS crystals with clover-like structure: preparation, characterization, optical properties and influencing factor”, Cryst. Res. Technol., 2004, 39(3), 198-204.

164. Y. Xu, Z. Zhu, Z. Xu,* “Liquid crystalline thiadiazole perivatives: thiadiazole derivatives containing pyriding ring as terminal group”, Chin. J. Chem., 2001, 19, 870-876.

165. G. Yin, X. Mao, Z. Suo, Z. Xu,* “Synthesis and electronic properties of C60-carbazole adducts”, Chin. J. Chem., 2001, 19, 822-828.

166. H. B. Liu, Z. Xu,* et al., “Crystal structure and luminescence of [Eu(TTA)3•DAF] •0.5C7H8 complex excited by visible light”, Chin. J. Chem., 2001, 19, 766-771.

167. X. P. Shen, Z. Xu*, et al., “A new two dimensional cyano-bridged chromium (III)-Nickel (II) bimetallic assemly with stair-like layers”, Chinese J. Chem., 2001, 19(6), 627-629.

168. Y. Wu, Z. Xu,* “Aminolysis reaction of calyx[4]arene esters and crystal structures and conformation behavior of calyx(4) arene amide”, Chin. J. Chem., 2000, 18(1), 94-103.

169. M. Li, X. Chen, J. Zou, Z. Xu,* “A spectral study of single meso-(hydroxylthenyl) octamethylporphyrins”, Chin. J. Chem., 1996, 14(1), 20.

170. M. Li, Z. Xu,* et al., “Synthesis, spectroscopic properties and tautomerism of mono-meso-substituted-octamethylporphyrins”, Chin. J. Chem., 1994, 12(3), 237.

171. S. Gou, P. Zheng, Z. Xu,* et al., “Synthesis and structure of a new polynuclear complex with a monomer of (3, 4, 9, 10-dibenzo-1, 12-diaza-5, 8-diox-acyclopentadecane)copper(II) (μ-Cl)2] zine(II) chloride”, Chin. J. Chem., 1992, 10(3), 232.

172. B. L. Li, Z. Xu,* et al., “Synthesis, structure and characterization of two-dimension network copper complexes [Cu3(nta)2(azpy)2(H2O)2]•6H2O”, Chin. J. Chem., 2002, 20, 187-190.

173. Q. Liu, Z. Xu,* et al., “Diaquabis(hexamethylenetetsamine-N) bis(isothiocyanato) -manganese(Ⅱ) etraquabis(isothiocyanato) manganese(Ⅱ) dihydrate”, Acta Cryst. E, 2001, 57, m151-m153.

174. B. L. Li, X. P. Shen, J. Z. Zou, Z. Xu,* et al., “A three-dimensional porous framework complex, poly[[bis(ethylenediamine)copper(II)] [potassium hexacyanocobalt(III)]]”, Acta Cryst. C, 2001, 57, 1242-1244. 0.719

175. B. L. Li, X. W. Wei, Z. Xu,* “Synthesis and crystal structure of [Cu(TTA)2]2•C2H3N3CH2CH2 C2H3N3”, Acta. Cryst. C., 1999, 55, 165-167.

176. W. Chen, J. Z. Zuo, Z. Xu,* et al., “A tetracarboxylatobenzene-bridged binuclear copper(II) complex”, Acta Cryst. C, 1996, 52(1), 43.

177. D. L. Zhu, Y. P. Yu, Z. Xu,* et al., “Catena-poly[Bis(O, O')-diethyldithiophosphato-S' Zinc-μ-(4, 4,)-bipyridyl-N:N']”, Acta. Cryst. C., 1996, 52, 1963.

178. X. G. Zhou, Z. Ma, X. Z. You, Z. Xu,* “Benzopyenone adduct of triscyclopentadienyl dysprosium”, Acta. Cryst. C., 1996, 52, 187.

179. E. C. Alyea, G. Ferguson, Z. Xu,* “Hydrogen-bonded self-assembly of 2, 2', 2''-triamino triethylamine molybdrate, 4[N(CH2CH2NH3)2+]3•6[MoO4]2-•6H2O” Acta Cryst. C, 1995, 51, 353.

180. J. Zou, Z. Xu*, M. Li, et al., “7, 8, 17, 18-Tetrabromo- 5, 10, 15, 20-tetra -phenylporphyrin”, Acta Cryst. C, 1995, 51, 760.

181. G. Ferguson, E. C. Alyea, Z. Xu,* “The crystal structure of the copper tripodal schiff base complex, {Tris-[4-(2-thienyl)-3-aza-KN-butaenyl]amine-KN}Copper(I) Tetrafluoroborate”, Acta Cryst. C, 1994, 50, 16.

182. M. Li, Z. Xu,* et al., “Binuclear copper(II) complex: bis[4, 4, 4-trifluoro-1-(2-thienyl)butane-1, 3-dionato-O, O']copper(II) bridged by 4, 4'-bipyridine”, Acta Cryst. C, 1994, 50. 1699.

183. S. Gou, X. You, Z. Xu,* et al., “Structure of catena-poly {bis[1, 1, 1, -trifluorobutane -1, 3-dionato-K2]O, O'} copper-μ-(4, 4'- bipyridine)-KN,KN'}}”, Acta Cryst. C, 1991, 47, 2653.

184. S. Gou, Z. You, Z. Xu,* et al., “Catena-poly {bis[1-(2-thienyl) -4, 4, 4-trifluorobutane -1, 3- butanedionato-K2] O, O'} copper-μ-(4, 4'-bipyridine) -KN:KN'} -N, N-dimethylformamide(1/2)”, Acta Cryst. C, 1991, 47, 1303.

185. S. Liu, Z Xu,* et al., “Structure of a five-coordinated nickel complex: [Ni{(C2H5O)2PS2}2 P(C6H5)3]”, Acta Cryst. C, 1991, 47, 43.

186. S. Gou, Z. You, Z. Xu,* et al., “Structure of 2,2'-[5-(2-Aminoethyl)-1-hydroxy-2,5,8-triazanon-3-en-1,9-diyl]bis(pyridine-N-oxid)nickel hexafluorophosphate hydrate: A novel tripodal nickel(II) complex with three inequivalent arms”, Acta Cryst. C, 1991, 47, 708.

187. Z. Xu*, S. Gou, et al., “Structure of a five-coordinate copper(II) complex of (2,2'-bipyridine) [4,4,4- trifluoro-1- (2-thienyl) butane-1,3-dionato-O] [4,4,4-trifluoro-1-(2-thienyl) butane-1,3- dionato-O,O'] copper(II)”, Acta Cryst. C, 1991, 47, 81.

188. E. C. Alyea, Z. Xu,* et al., “Structure of a copper(I) complex of a tripodal schiff base ligand, tris[4-(2-thienyl)-3-aza-butenyl]amine copper(I) triiodide chloroform solvate”, Acta Cryst. C, 1990, 46, 2347.

189. J. Huang, Y. Yu, Z. Xu,* et al., “Structure of the adduct of bis(O,O'-dibutyldithiophosphato)nickel(II) with imidazole”, Acta Cryst. C, 1990, 46, 991.

190. X. Z. You, J. Chen, Z. Xu,* et al., “Structure of hexakis (isopropylammonium) diformyloctamolybdate”, Acta Cryst. C, 1989, 45, 413.

191. E. C. Alyea, Z. Xu,* et al., “Structure of a potentially heptadentate tripodal ligand tris[4-(2-thienyl)-3-aza-3-butenyl]amine”, Acta Cryst. C, 1989, 45, 1566.

192. Q. F. Zhou, Z. Xu,* et al., “A novel shape-selection fabrication of nanostructured silver”, Science in China B, 2002, 45, 416-420.

193. G. Yin, Z. Xu,* “Synthesis of water-soluble C60 derivatives and their scavenging free radical activity”, Science in China B, 2002, 45(1), 54-59.

194. X. W. Wei, M. F. Wu, Z. Xu,* et al., “Addition reaction of buckminsterfullerene with amines and electrospray ionization mass spectrometry determination of reaction products”, Chem. J. Chin. Univ., 1996, 17, 1570.

195. J.-C. Bao, X. Ni, Z. Xu,* et al., “Synthesis and magnetic exchange interaction of heterobinuclear Cu(II)-Co(II) complexes” Chem. J. Chin. Univ., 1994, 15(2), 178.

196. M. X. Li, Z. Xu* et al., “Synthesis, crystal structure and properties of TAAB nickel adducts with axial N-base ligands”, Chem. J. Chin. Univ., 1993, 14(6), 745.

197. Z. Z. Wu, Z. Xu,* et al., “Synthesis and studies on thermal stability of dicyclopentadienyl lanthanide 8-hydroxyquinolinolato complexes”, Chem. J. Chin. Univ., 1993, 14(1), 9.

198. Y. P. Yu, Z. Xu,* et al., “Synthesis and crystal structure of the complex of bis[4, 4, 4-trifluoro-1-(2-thienyl)butanedione-1,3]copper(II) with diquinoline”, Chem. J. Chin. Univ., 1991, 12(2), 157.

199. K. B. Yu, S. H. Gou, Z. Xu,* et al., “Crystal and molecular structure of copper (II) dimeric complex of S-methyl-β-N-(pyridine N-oxide-2-ylmethylidene) dithio- carbazate with Acetonitrile”, Chem. J. Chin. Univ., 1991, 12(7), 869.

200. Y. P. Yu, Z. Xu,* et al., “Study on the thermodynamic properties of adduction reaction between Ni[(C8H17O)2PS2]2 and aldehydes by GLC method”, Chem. J. Chin. Univ. 1990, 11(5), 551.

201. K. Yu, S. Gou, Z. Xu,* et al., “Crystal and molecular structure of copper (II) dimeric complex of S-methyl-N- (pyridine N-oxide-2- ylmethylidene) dithiocarbazate with acetonitrile”, Chem. J. Chin. Univ., 1990, 11(4), 262.

202. S, Gou, X. You, Z. Xu,* et al., “Synthesis and magnetic properties of copper(II) complexes with pyridine N-oxide-2-ylmethylidene dithiocarbazate as ligands”, Chem. J. Chin. Univ., 1990, 11(4), 255.

203. S. X. Liu, Z. Xu,* et al., “Determination of equilibrium constants for the adductive reaction of bis-(O, O'-Dicyclohexyl-dithiophosphato) Nickel (II) with pyridine and the crystal structure of Ni[(C6H11O)2PS2]2•2Py”, Chem. J. Chin. Univ., 1989, 10(12), 1225.

204. Z. Xu,* et al., “Synthesis and crystal structure of tri-(O, O'- Diethyldithio phosphato) Cobalt (III)”, Chem. J. Chin. Univ., 1988, 9(5), 432.

205. Y. P. Yu, Z. Xu,* et al., “Determination of thermodynamic parameters of adduct reaction of Ni[(C8H17O)2PS2]2 and (C2H5)3N by GLC Method”, Chem. J. Chin. Univ., 1988, 9(1), 9.

206. H. Li, Z. Xu,* et al., “Self-assembly of gold nanoparticles monolayer film at water/oil interface”, Chin. J. Inorg. Chem., 2008, 24, 1664-1668.

207. M. Han, Z. Xu,* et al., “Synthesis, characterization and electrochemical properties of multi-layered porous Co3O4 nanoparticle assemblies”, Chin. J. Inorg. Chem., 2008, 24, 797-802.

208. D. M. Zhu, Z. Xu,* et al., “Preparation and characterization of inorganic-polymer-inorganic multicomponent core-shell nanocomposite material”, Chin. J. Inorg. Chem., 2007, 23, 2128.

209. W. L. Zhang, Z. Xu,* et al., “Scheelite BaWO4 nanowire bundles: controllable synthesis and optical properties”, Chin. J. Inorg. Chem., 2007, 23, 1796.

210. X. P. Shen, Z. Xu,* et al., “Hydrothermal synthesis of Sb2S3 nanorod ordered arrays”, Chin. J. Inorg. Chem., 2007, 23, 1561.

211. T. M. Shang, Z. Xu,* et al., “A new photochromic film: Na2WO4-PAA-glycerol system”, Chin. J. Inorg. Chem., 2007, 23, 124.

212. M. Han, Z. Xu,* et al., “Synthesis and optical properties of alpha-ZnS single crystalline nanowire bundles”, Chin. J. Inorg. Chem., 2006, 22, 1585-1590.

213. X. W. Wei, Z. Xu,* et al., “Synthesis and photophysical properties of fullerene derivatives”, Fullerene nanotubes and carbon nanostructures, 2002, 10(2), 137-153.

214. B. L. Li, Y. Xu, Y. J. Liu, Z. Xu,* “Synthesis, structure and magnetic properties of an interlock network frame of cobalt (II) coordination polymer {[Co(azpy)2(NCS)2]•1/4EtOH•1/2H2O}n ”, Chem. Res. Chin. Uni., 2001, 17(3), 237-242.

215. S. W. Wang, X. W. Wei, L. Qi, Z. Xu,* “Synthesis and characterization of divalent organolanthanide-fullerene adducts Cp2LnC60(Ln=Yb,Sm):first example of insertion reaction involving cyclopentadienyl and fullerene”, Fullerene Sci. and Techn., 1998, 6(6), 1087.

216. Z. Suo, X. Wei, Y. Mei, Z. Xu,* “Group transfer and dimerization processes of C60(CN)2 in atomspheric ionization conditions”, Fullerene Sci. and Techn., 2001, 9(2), 211-223.

217. X. Wei, Z. Suo, Z. Xu,* “Syntheses and characterization of some organic dye buckminsterfulleride”, Fullerene Sci. and Technol., 1999, 7, 781-793.

218. Y. Wu, Z. Xu,* et al., “A facile method of synthesis of calix(4)arene amide and the first example of a self-assembly calix(4)arene via van der waals interaction”, J. Inclusion Phenomena Chem., 2000, 36(4), 473-476.

219. X. Z. You, H. W. Chen, Z. Xu,* “metal cluster chemistry”, Chemistry Bulletin, 1985, 9, 5.

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